Lithiated porous aromatic frameworks with exceptional gas storage capacity

Kristina Konstas, James W Taylor, Aaron William Thornton, Cara M Doherty, Wei Xian Lim, Timothy J Bastow, Danielle F Kennedy, Colin D Wood, Barry J Cox, James M Hill, Anita J Hill, Matthew Roland Hill

Research output: Contribution to journalArticleResearchpeer-review

87 Citations (Scopus)

Abstract

A porous treasure: Porous aromatic framework PAF-1 (see picture, blue structure) has been lithiated, giving a reduced framework with an increased gas storage capacity compared to native PAF-1 (by 22, 71, and 320 for H 2, CH 4, and CO 2, respectively). The reduced framework was examined spectroscopically, and the potential hydrogen storage capacity was calculated.
Original languageEnglish
Pages (from-to)6639 - 6642
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number27
DOIs
Publication statusPublished - 2012
Externally publishedYes

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