Light olefin production from CO/H2 over silica supported Fe/Mn/K catalysts derived from a bimetallic carbonyl anion, [Fe2Mn(CO)12]-

L. Bruce; G. Hope; T. W. Turney

doi:10.1007/BF02063605

Light olefin production from CO/H₂ over silica supported Fe/Mn/K catalysts derived from a bimetallic carbonyl anion, [Fe₂Mn(CO)₁₂]^-

L. Bruce, G. Hope, T. W. Turney

Research output: Contribution to journal › Article › Research › peer-review

31 Citations (Scopus)

Abstract

Fe/Mn/K catalysts derived from support of the anionic carbonyl, [Fe₂Mn(CO)₁₂]^- on silica were compared with catalysts prepared by aqueous impregnation methods, and found to be more selective for production of C₂-C₄ olefins. Addition of K had little effect, whereas variations in reaction conditions altered selectivity owing to secondary reactions of the alkene products.

Original language	English
Pages (from-to)	175-180
Number of pages	6
Journal	Reaction Kinetics and Catalysis Letters
Volume	20
Issue number	1-2
DOIs	https://doi.org/10.1007/BF02063605
Publication status	Published - 1 Mar 1982
Externally published	Yes

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title = "Light olefin production from CO/H2 over silica supported Fe/Mn/K catalysts derived from a bimetallic carbonyl anion, [Fe2Mn(CO)12]-",

abstract = "Fe/Mn/K catalysts derived from support of the anionic carbonyl, [Fe2Mn(CO)12]- on silica were compared with catalysts prepared by aqueous impregnation methods, and found to be more selective for production of C2-C4 olefins. Addition of K had little effect, whereas variations in reaction conditions altered selectivity owing to secondary reactions of the alkene products.",

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AU - Hope, G.

AU - Turney, T. W.

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N2 - Fe/Mn/K catalysts derived from support of the anionic carbonyl, [Fe2Mn(CO)12]- on silica were compared with catalysts prepared by aqueous impregnation methods, and found to be more selective for production of C2-C4 olefins. Addition of K had little effect, whereas variations in reaction conditions altered selectivity owing to secondary reactions of the alkene products.

AB - Fe/Mn/K catalysts derived from support of the anionic carbonyl, [Fe2Mn(CO)12]- on silica were compared with catalysts prepared by aqueous impregnation methods, and found to be more selective for production of C2-C4 olefins. Addition of K had little effect, whereas variations in reaction conditions altered selectivity owing to secondary reactions of the alkene products.

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Light olefin production from CO/H2 over silica supported Fe/Mn/K catalysts derived from a bimetallic carbonyl anion, [Fe2Mn(CO)12]-

Abstract

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Light olefin production from CO/H₂ over silica supported Fe/Mn/K catalysts derived from a bimetallic carbonyl anion, [Fe₂Mn(CO)₁₂]^-