Ligand field and molecular orbital theories of transition metal x-ray absorption edge transitions

Rosalie Katherine Hocking, Edward I Solomon

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34 Citations (Scopus)


Carl Ballhausen made a wide range of seminal contributions to ligand field theory and its application to ground state and ligand field excited state spectroscopies. These provided a fundamental basis for probing the nature of transition metal complexes using their visible spectra and a range of magnetic spectroscopies. The advent of synchrotrons provided access to high flux electromagnetic radiation that could be tuned across a wide range of energies including X-ray. This expanded the scope of spectroscopic techniques available to inculde X-ray Absorption Edge Spectroscopies. Paralleling a visible absorption experiment, X-ray spectra (metal K-edge, i.e. 1s->3d and metal L-edge, i.e. 2p->3d) taken at a synchrotron are dominated by ligand field splittings, electron repulsion effects and covalency. These can be used to obtain important insight into the properties of a diverse range of materials from solar cells to the catalytic centers of metalloenzymes. Herein we systematically consider applications of ligand field theory to X-ray absorption edge transitions.
Original languageEnglish
Pages (from-to)155 - 184
Number of pages30
JournalStructure and Bonding
Publication statusPublished - 2012

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