Ligand effects in a heteroleptic bis-tridentate iron(III) spin crossover complex showing a very high T1/2 value

Wasinee Phonsri; Victor Martinez; Casey G Davies; Guy N L Jameson; Boujemaa Moubaraki; Keith S Murray

doi:10.1039/c5cc08701e

Ligand effects in a heteroleptic bis-tridentate iron(III) spin crossover complex showing a very high T_1/2 value

Wasinee Phonsri, Victor Martinez, Casey G Davies, Guy N L Jameson, Boujemaa Moubaraki, Keith S Murray

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

30 Citations (Scopus)

Abstract

We describe the first example of a bis-tridentate heteroleptic iron(iii) spin crossover (SCO) complex, [Fe(3-OMe-SalEen)(thsa)]. Compared to the parent homoleptic compounds, the spin crossover features in the heteroleptic species are enhanced with a gradual-abrupt spin transition at 344 K. Clear correlations between π-π interactions and the T_1/2 value have been revealed.

Original language	English
Pages (from-to)	1443-1446
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	7
DOIs	https://doi.org/10.1039/c5cc08701e
Publication status	Published - 2016

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10.1039/c5cc08701e

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AU - Davies, Casey G

AU - Jameson, Guy N L

AU - Moubaraki, Boujemaa

AU - Murray, Keith S

PY - 2016

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AB - We describe the first example of a bis-tridentate heteroleptic iron(iii) spin crossover (SCO) complex, [Fe(3-OMe-SalEen)(thsa)]. Compared to the parent homoleptic compounds, the spin crossover features in the heteroleptic species are enhanced with a gradual-abrupt spin transition at 344 K. Clear correlations between π-π interactions and the T1/2 value have been revealed.

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Ligand effects in a heteroleptic bis-tridentate iron(III) spin crossover complex showing a very high T_1/2 value

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Multifunctional hybrid spin crossover materials

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Ligand effects in a heteroleptic bis-tridentate iron(III) spin crossover complex showing a very high T1/2 value

Abstract

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Multifunctional hybrid spin crossover materials

Cite this

Ligand effects in a heteroleptic bis-tridentate iron(III) spin crossover complex showing a very high T_1/2 value