Lifting the lid on metatungstate, 1H and 183W NMR study of the six electron reduced anion [(H)2(W(IV)3(OH2)3)W(VI)9O34(OH)3]3-

Colette Boskovic, Maruse Sadek, Robert T.C. Brownlee, Alan M. Bond, Anthony G. Wedd

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Abstract

The distribution of the eleven protons present in a six-electron reduced form of metatungstate, [(H)2(W(IV)3-(OH2)3)W(VI)9O34(OH)3]3-, in dry CD3CN is mapped by 1H and 183W NMR, allowing assessment of structural changes which accompany reduction.

Original languageEnglish
Pages (from-to)533-534
Number of pages2
JournalChemical Communications
Issue number6
DOIs
Publication statusPublished - 21 Mar 1999

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