Abstract
The effect of careful control over metal and oxygen stoichiometry on the structures of various Mn+1M′n+1 O3n+5 phases (M = La and/or Sr, M′ = Ti and/or Nb) has been studied by transmission electron microscopy. In addition to the previously reported n = 3 and 4 layered phases and the n = ∝ parent perovskite, ordered and disordered intergrowth structures comprising the n = 2, 3, 4, and ∝ members have been characterized. The effects of in situ reduction in the electron microscope were studied.
Original language | English |
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Pages (from-to) | 375-386 |
Number of pages | 12 |
Journal | Journal of Solid State Chemistry |
Volume | 103 |
Issue number | 2 |
DOIs | |
Publication status | Published - 1 Jan 1993 |
Externally published | Yes |