Large-scale synthesis of α-Si3N4 nanofibers and nanobelts from mesoporous silica-carbon nanocomposites

K. Wang, H. Wang, Y.-B. Cheng

Research output: Contribution to journalArticleResearchpeer-review

Abstract

This work presents a low-cost and large-scale synthesis technique for silicon nitride nanofibers and nanobelts based on the use of mesoporous silica-carbon nanocomposites as precursors via a carbothermal reduction and nitridation reaction. The growth mechanisms have been investigated by carrying out heat-treatment of precursors with different C/SiO2 ratios in a flowing nitrogen gas with different flow rates. Highly crystalline silicon nitride nanofibers and nanobelts were obtained after easy separation from the unreacted powder underneath. A higher C/SiO2 ratio gives a better yield of nitride products. The thickness of the ribbons can be maintained as constant while the width of the ribbons can be controlled by tailoring the flow rate of nitrogen gas. The growth direction of Si3N4 nanobelts is parallel to the [100] crystallographic orientation of a-Si3N4.

Original languageEnglish
Pages (from-to)259-264
Number of pages6
JournalJournal of Ceramic Science and Technology
Volume8
Issue number2
DOIs
Publication statusPublished - 1 Jun 2017

Keywords

  • Carbothermal reduction and nitridation
  • Mesoporous
  • Nanobelts
  • Nanocomposites
  • Nanofibers
  • Silicon nitride

Cite this

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title = "Large-scale synthesis of α-Si3N4 nanofibers and nanobelts from mesoporous silica-carbon nanocomposites",
abstract = "This work presents a low-cost and large-scale synthesis technique for silicon nitride nanofibers and nanobelts based on the use of mesoporous silica-carbon nanocomposites as precursors via a carbothermal reduction and nitridation reaction. The growth mechanisms have been investigated by carrying out heat-treatment of precursors with different C/SiO2 ratios in a flowing nitrogen gas with different flow rates. Highly crystalline silicon nitride nanofibers and nanobelts were obtained after easy separation from the unreacted powder underneath. A higher C/SiO2 ratio gives a better yield of nitride products. The thickness of the ribbons can be maintained as constant while the width of the ribbons can be controlled by tailoring the flow rate of nitrogen gas. The growth direction of Si3N4 nanobelts is parallel to the [100] crystallographic orientation of a-Si3N4.",
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Large-scale synthesis of α-Si3N4 nanofibers and nanobelts from mesoporous silica-carbon nanocomposites. / Wang, K.; Wang, H.; Cheng, Y.-B.

In: Journal of Ceramic Science and Technology, Vol. 8, No. 2, 01.06.2017, p. 259-264.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Large-scale synthesis of α-Si3N4 nanofibers and nanobelts from mesoporous silica-carbon nanocomposites

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AU - Wang, H.

AU - Cheng, Y.-B.

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AB - This work presents a low-cost and large-scale synthesis technique for silicon nitride nanofibers and nanobelts based on the use of mesoporous silica-carbon nanocomposites as precursors via a carbothermal reduction and nitridation reaction. The growth mechanisms have been investigated by carrying out heat-treatment of precursors with different C/SiO2 ratios in a flowing nitrogen gas with different flow rates. Highly crystalline silicon nitride nanofibers and nanobelts were obtained after easy separation from the unreacted powder underneath. A higher C/SiO2 ratio gives a better yield of nitride products. The thickness of the ribbons can be maintained as constant while the width of the ribbons can be controlled by tailoring the flow rate of nitrogen gas. The growth direction of Si3N4 nanobelts is parallel to the [100] crystallographic orientation of a-Si3N4.

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KW - Nanobelts

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