Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

Megan K Thorson; Phuc Ung; Franklin M Leaver; Teresa S Corbin; Kellie L Tuck; Bim Graham; Amy M Barrios

doi:10.1016/j.aca.2015.09.024

Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

Megan K Thorson, Phuc Ung, Franklin M Leaver, Teresa S Corbin, Kellie L Tuck, Bim Graham, Amy M Barrios

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

A series of lanthanide-based, azide-appended complexes were investigated as hydrogen sulfide-sensitive probes. Europium complex 1 and Tb complex 3 both displayed a sulfide-dependent increase in luminescence, while Tb complex 2 displayed a decrease in luminescence upon exposure to NaHS. The utility of the complexes for monitoring sulfide levels in industrial oil and water samples was investigated. Complex 3 provided a sensitive measure of sulfide levels in petrochemical water samples (detection limit ~ 250 nM), while complex 1 was capable of monitoring μM levels of sulfide in partially refined crude oil.

Original language	English
Pages (from-to)	160-165
Number of pages	6
Journal	Analytica Chimica Acta
Volume	896
DOIs	https://doi.org/10.1016/j.aca.2015.09.024
Publication status	Published - 2015

Keywords

Azide reduction
Crude oil
Hydrogen sulfide
Lanthanide luminescence
Time-resolved luminescence

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10.1016/j.aca.2015.09.024

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title = "Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples",

abstract = "A series of lanthanide-based, azide-appended complexes were investigated as hydrogen sulfide-sensitive probes. Europium complex 1 and Tb complex 3 both displayed a sulfide-dependent increase in luminescence, while Tb complex 2 displayed a decrease in luminescence upon exposure to NaHS. The utility of the complexes for monitoring sulfide levels in industrial oil and water samples was investigated. Complex 3 provided a sensitive measure of sulfide levels in petrochemical water samples (detection limit \textasciitilde{} 250 nM), while complex 1 was capable of monitoring μM levels of sulfide in partially refined crude oil.",

keywords = "Azide reduction, Crude oil, Hydrogen sulfide, Lanthanide luminescence, Time-resolved luminescence",

author = "Thorson, \{Megan K\} and Phuc Ung and Leaver, \{Franklin M\} and Corbin, \{Teresa S\} and Tuck, \{Kellie L\} and Bim Graham and Barrios, \{Amy M\}",

year = "2015",

doi = "10.1016/j.aca.2015.09.024",

language = "English",

volume = "896",

pages = "160--165",

journal = "Analytica Chimica Acta",

issn = "0003-2670",

publisher = "Elsevier BV",

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T1 - Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

AU - Thorson, Megan K

AU - Ung, Phuc

AU - Leaver, Franklin M

AU - Corbin, Teresa S

AU - Tuck, Kellie L

AU - Graham, Bim

AU - Barrios, Amy M

PY - 2015

Y1 - 2015

N2 - A series of lanthanide-based, azide-appended complexes were investigated as hydrogen sulfide-sensitive probes. Europium complex 1 and Tb complex 3 both displayed a sulfide-dependent increase in luminescence, while Tb complex 2 displayed a decrease in luminescence upon exposure to NaHS. The utility of the complexes for monitoring sulfide levels in industrial oil and water samples was investigated. Complex 3 provided a sensitive measure of sulfide levels in petrochemical water samples (detection limit ~ 250 nM), while complex 1 was capable of monitoring μM levels of sulfide in partially refined crude oil.

AB - A series of lanthanide-based, azide-appended complexes were investigated as hydrogen sulfide-sensitive probes. Europium complex 1 and Tb complex 3 both displayed a sulfide-dependent increase in luminescence, while Tb complex 2 displayed a decrease in luminescence upon exposure to NaHS. The utility of the complexes for monitoring sulfide levels in industrial oil and water samples was investigated. Complex 3 provided a sensitive measure of sulfide levels in petrochemical water samples (detection limit ~ 250 nM), while complex 1 was capable of monitoring μM levels of sulfide in partially refined crude oil.

KW - Azide reduction

KW - Crude oil

KW - Hydrogen sulfide

KW - Lanthanide luminescence

KW - Time-resolved luminescence

UR - http://goo.gl/fbnXpY

UR - https://www.scopus.com/pages/publications/84944402186

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DO - 10.1016/j.aca.2015.09.024

M3 - Article

SN - 0003-2670

VL - 896

SP - 160

EP - 165

JO - Analytica Chimica Acta

JF - Analytica Chimica Acta

ER -

Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

Abstract

Keywords

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Expanding the molecular tool set for structural studies of proteins and their complexes

Cite this

Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

Abstract

Keywords

Access to Document

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Expanding the molecular tool set for structural studies of proteins and their complexes

Cite this