Lacunary tungstotellurates(IV): [Te2W17O 61]12-,[Te2W16O58(OH) 2]14- and [Te2W18O 62(OH)2]10-

Chris Ritchie, Kerwyn G. Alley, Colette Boskovic

Research output: Contribution to journalArticleResearchpeer-review

15 Citations (Scopus)

Abstract

A simple procedure is reported for the isolation of the new lacunary tungstotellurate(iv) [Te2W17O61]12- (1a) in multi-gram quantities, with 125Te and 183W NMR spectroscopy indicating retention of the solid state structure in solution. The structurally related polyanions [Te2W16O 58(OH)2]14- (2a) and [Te2W 18O62(OH)2]10- (2b) were also isolated.

Original languageEnglish
Pages (from-to)8872-8874
Number of pages3
JournalDalton Transactions
Volume39
Issue number38
DOIs
Publication statusPublished - 14 Oct 2010
Externally publishedYes

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