Kinetic and mechanistic similarities between reversible addition fragmentation chain transfer intermediate and acrylate midchain radicals

Christopher Barner-Kowollik; Thomas Junkers

doi:10.1002/pola.24546

Kinetic and mechanistic similarities between reversible addition fragmentation chain transfer intermediate and acrylate midchain radicals

Christopher Barner-Kowollik, Thomas Junkers

Research output: Contribution to journal › Article › Research › peer-review

19 Citations (Scopus)

Abstract

This contribution highlights the mechanistic and kinetic similarities as well as differences between midchain radicals occurring in both acrylate free radical polymerization as well as reversible addition fragmentation chain transfer mediated processes.

Original language	English
Pages (from-to)	1293-1297
Number of pages	5
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	49
Issue number	5
DOIs	https://doi.org/10.1002/pola.24546
Publication status	Published - 1 Mar 2011
Externally published	Yes

Keywords

acrylate free radical polymerization
kinetics (polym.)
macromonomers
midchain radicals (MCRs)
reversible addition fragmentation chain transfer (RAFT)

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10.1002/pola.24546

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title = "Kinetic and mechanistic similarities between reversible addition fragmentation chain transfer intermediate and acrylate midchain radicals",

abstract = "This contribution highlights the mechanistic and kinetic similarities as well as differences between midchain radicals occurring in both acrylate free radical polymerization as well as reversible addition fragmentation chain transfer mediated processes.",

keywords = "acrylate free radical polymerization, kinetics (polym.), macromonomers, midchain radicals (MCRs), reversible addition fragmentation chain transfer (RAFT)",

author = "Christopher Barner-Kowollik and Thomas Junkers",

year = "2011",

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T1 - Kinetic and mechanistic similarities between reversible addition fragmentation chain transfer intermediate and acrylate midchain radicals

AU - Barner-Kowollik, Christopher

AU - Junkers, Thomas

PY - 2011/3/1

Y1 - 2011/3/1

N2 - This contribution highlights the mechanistic and kinetic similarities as well as differences between midchain radicals occurring in both acrylate free radical polymerization as well as reversible addition fragmentation chain transfer mediated processes.

AB - This contribution highlights the mechanistic and kinetic similarities as well as differences between midchain radicals occurring in both acrylate free radical polymerization as well as reversible addition fragmentation chain transfer mediated processes.

KW - acrylate free radical polymerization

KW - kinetics (polym.)

KW - macromonomers

KW - midchain radicals (MCRs)

KW - reversible addition fragmentation chain transfer (RAFT)

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DO - 10.1002/pola.24546

M3 - Article

AN - SCOPUS:79251629976

SN - 0887-624X

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SP - 1293

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JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 5

ER -

Kinetic and mechanistic similarities between reversible addition fragmentation chain transfer intermediate and acrylate midchain radicals

Abstract

Keywords

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