Abstract
Simple source: An intramolecular iridium-mediated C-H borylation proceeds through transfer of a BH3 fragment from borohydride to a benzylic carbon center (see scheme; coe=cyclooctene). Simple and inexpensive LiBH 4 is thus utilized as the boron source in C-H to C-B conversion.
Original language | English |
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Pages (from-to) | 1359-1362 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 50 |
Issue number | 6 |
DOIs | |
Publication status | Published - 7 Feb 2011 |
Externally published | Yes |
Keywords
- boron
- borylation
- C-H activation
- iridium
- N-heterocyclic ligands