TY - JOUR
T1 - Interlaminar fracture toughness behaviour of carbon fibre reinforced polymer with epoxy-dicarboxylic acid vitrimer matrix
AU - Tangthana-umrung, Kanokporn
AU - Gresil, Matthieu
N1 - Publisher Copyright:
© 2022 Elsevier Ltd
PY - 2022/6
Y1 - 2022/6
N2 - Healable and recyclable fibre reinforced vitrimer composites have been developed by taking advantage of the mechanical strength and topological rearrangement via bond exchange reaction. While the tensile properties of vitrimer laminates have been extensively studied, interlaminar properties have yet to be demonstrated. Experiments on mode I interlaminar fracture toughness and flexural characteristics of carbon fibre reinforced polymer (CFRP) composites based on epoxy-dicarboxylic acid vitrimer with various epoxy:acid ratios are presented in this paper. By hand lay-up and hot press, two vitrimer laminates with epoxy:acid ratio of 1:0.5 (off-stoichiometric, C50/CF) and 1:1 (stoichiometric, C100/CF) were successfully fabricated. From the flexural test, both C50/CF and C100/CF reveal marvellous stiffness of ∼60 GPa. Additionally, C50/CF also shows excellent flexural strength of 821 MPa which is in a similar range to conventional anhydride epoxy CFRP composites. In terms of interlaminar fracture properties under mode I loading, vitrimer CFRP composites outperform standard epoxy laminates on mode I fracture energy at initiation and propagation zones. At the initiation stage, fracture energies of C50/CF and C100/CF are two times higher than those of epoxy/CF. Furthermore, the average fracture energies during crack propagation of C50/CF and C100/CF were increased by ∼42% and ∼63%, respectively, when compared to epoxy/CF. The fracture surfaces of vitrimer laminates revealed matrix residue on the fibres, demonstrating that vitrimer and carbon fibres had good interfacial adhesion. These findings revealed a huge potential for further development of vitrimer CFRP composites for advanced applications.
AB - Healable and recyclable fibre reinforced vitrimer composites have been developed by taking advantage of the mechanical strength and topological rearrangement via bond exchange reaction. While the tensile properties of vitrimer laminates have been extensively studied, interlaminar properties have yet to be demonstrated. Experiments on mode I interlaminar fracture toughness and flexural characteristics of carbon fibre reinforced polymer (CFRP) composites based on epoxy-dicarboxylic acid vitrimer with various epoxy:acid ratios are presented in this paper. By hand lay-up and hot press, two vitrimer laminates with epoxy:acid ratio of 1:0.5 (off-stoichiometric, C50/CF) and 1:1 (stoichiometric, C100/CF) were successfully fabricated. From the flexural test, both C50/CF and C100/CF reveal marvellous stiffness of ∼60 GPa. Additionally, C50/CF also shows excellent flexural strength of 821 MPa which is in a similar range to conventional anhydride epoxy CFRP composites. In terms of interlaminar fracture properties under mode I loading, vitrimer CFRP composites outperform standard epoxy laminates on mode I fracture energy at initiation and propagation zones. At the initiation stage, fracture energies of C50/CF and C100/CF are two times higher than those of epoxy/CF. Furthermore, the average fracture energies during crack propagation of C50/CF and C100/CF were increased by ∼42% and ∼63%, respectively, when compared to epoxy/CF. The fracture surfaces of vitrimer laminates revealed matrix residue on the fibres, demonstrating that vitrimer and carbon fibres had good interfacial adhesion. These findings revealed a huge potential for further development of vitrimer CFRP composites for advanced applications.
KW - CFRP
KW - Interlaminar fracture toughness
KW - Vitrimer
UR - http://www.scopus.com/inward/record.url?scp=85130399687&partnerID=8YFLogxK
U2 - 10.1016/j.coco.2022.101182
DO - 10.1016/j.coco.2022.101182
M3 - Article
AN - SCOPUS:85130399687
SN - 2452-2139
VL - 32
JO - Composites Communications
JF - Composites Communications
M1 - 101182
ER -