Insertion of SO2 into a Sulfide-Bridged M-Ge Bond: Synthesis, Characterization, and Reactivity of the O-Germyl-S-sulfoxylate

Zuzanna T. Cygan; Jeff W. Kampf; Mark M.Banaszak Holl

Insertion of SO₂ into a Sulfide-Bridged M-Ge Bond: Synthesis, Characterization, and Reactivity of the O-Germyl-S-sulfoxylate

Zuzanna T. Cygan, Jeff W. Kampf, Mark M.Banaszak Holl

Research output: Contribution to journal › Article › Research › peer-review

Abstract

Addition of SO₂to (Et₃P)₂Pd(μ -S)Ge[N(SiMe₃)₂]₂ (1) results in the insertion of SO₂ into the Pd-Ge bond to give the O-germyl-S-sulfoxylate insertion isomer (Et₃P)₂Pd(μ-S)S(O)OGe[N(SiMe ₃)₂]₂ (2). Heating solutions of 2 results in the formation of (Et₃P)Pd(SGe[N(SiMe₃)₂] ₂OSOGe[N(SiMe₃)₂]₂S) (3) and a L_nPd(0) fragment. X-ray crystal structures of 2 and 3 are reported.

Original language	English
Pages (from-to)	2057-2063
Number of pages	7
Journal	Inorganic Chemistry
Volume	43
Issue number	6
Publication status	Published - 22 Mar 2004
Externally published	Yes

Cite this

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title = "Insertion of SO2 into a Sulfide-Bridged M-Ge Bond: Synthesis, Characterization, and Reactivity of the O-Germyl-S-sulfoxylate",

abstract = "Addition of SO2to (Et3P)2Pd(μ -S)Ge[N(SiMe3)2]2 (1) results in the insertion of SO2 into the Pd-Ge bond to give the O-germyl-S-sulfoxylate insertion isomer (Et3P)2Pd(μ-S)S(O)OGe[N(SiMe 3)2]2 (2). Heating solutions of 2 results in the formation of (Et3P)Pd(SGe[N(SiMe3)2] 2OSOGe[N(SiMe3)2]2S) (3) and a LnPd(0) fragment. X-ray crystal structures of 2 and 3 are reported.",

author = "Cygan, {Zuzanna T.} and Kampf, {Jeff W.} and Holl, {Mark M.Banaszak}",

year = "2004",

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T1 - Insertion of SO2 into a Sulfide-Bridged M-Ge Bond

T2 - Synthesis, Characterization, and Reactivity of the O-Germyl-S-sulfoxylate

AU - Cygan, Zuzanna T.

AU - Kampf, Jeff W.

AU - Holl, Mark M.Banaszak

PY - 2004/3/22

Y1 - 2004/3/22

N2 - Addition of SO2to (Et3P)2Pd(μ -S)Ge[N(SiMe3)2]2 (1) results in the insertion of SO2 into the Pd-Ge bond to give the O-germyl-S-sulfoxylate insertion isomer (Et3P)2Pd(μ-S)S(O)OGe[N(SiMe 3)2]2 (2). Heating solutions of 2 results in the formation of (Et3P)Pd(SGe[N(SiMe3)2] 2OSOGe[N(SiMe3)2]2S) (3) and a LnPd(0) fragment. X-ray crystal structures of 2 and 3 are reported.

AB - Addition of SO2to (Et3P)2Pd(μ -S)Ge[N(SiMe3)2]2 (1) results in the insertion of SO2 into the Pd-Ge bond to give the O-germyl-S-sulfoxylate insertion isomer (Et3P)2Pd(μ-S)S(O)OGe[N(SiMe 3)2]2 (2). Heating solutions of 2 results in the formation of (Et3P)Pd(SGe[N(SiMe3)2] 2OSOGe[N(SiMe3)2]2S) (3) and a LnPd(0) fragment. X-ray crystal structures of 2 and 3 are reported.

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M3 - Article

AN - SCOPUS:1642407783

SN - 0020-1669

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EP - 2063

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Insertion of SO2 into a Sulfide-Bridged M-Ge Bond: Synthesis, Characterization, and Reactivity of the O-Germyl-S-sulfoxylate

Abstract

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Insertion of SO₂ into a Sulfide-Bridged M-Ge Bond: Synthesis, Characterization, and Reactivity of the O-Germyl-S-sulfoxylate