Innovative process for the synthesis of vanadyl pyrophosphate as a highly selective catalyst for n-butane oxidation

Ali Asghar Rownaghi, Yun Hin Taufiq-Yap, Fateme Rezaei

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Vanadyl pyrophosphate (VPO) catalysts are used for the selective oxidation of light alkanes, which are based on vanadyl hydrogen phosphate hemihydrate (VOHPO4·0.5H2O) as the precursor. Catalyst precursor with well-defined crystal size has been successfully synthesized for the first time, using a simple one-step high-pressure autoclave that was surfactant-free and water-free method with significantly lower temperature and shorter reaction time. VOHPO4·0.5H2O was prepared from V2O5 using an isobutanol, 1-pentanol, 1-heptanol and 1-dectanol as both solvent and reducing agent at elevated temperatures (100, 120, and 150°C). This new method significantly reduced the preparation time and lowered production temperature (50%) of catalyst precursor (VOHPO4·0.5H2O) when compared to conventional hydrothermal synthesis methods. VOHPO4·0.5H2O can be obtained at temperature far below 150°C. It was found that the presence of 1-heptanol and 1-decanol in the reaction mixtures is crucial for obtaining a well-defined crystal size of precursor phase and solely generated impurity [VO(H2PO4)2]. Our findings show that both the phase composition and morphology of vanadium phosphate can be influenced by the use of different reducing agents and temperatures during the preparation process. This new methodology produces catalysts with a much higher surface area (ca. 23m2g-1) compared with those materials prepared by slow hydrothermal synthesis (ca. 9.5m2g-1). Finally, the yield of maleic anhydride was significantly increased from 21.3% for conventional catalyst to 37.9% for the new solvothermal catalyst. 

Original languageEnglish
Pages (from-to)328-335
Number of pages8
JournalChemical Engineering Journal
Volume165
Issue number1
DOIs
Publication statusPublished - 15 Nov 2010

Keywords

  • High-pressure autoclave
  • N-Butane oxidation
  • Solvothermal synthesis
  • Vanadyl hydrogen phosphate hemihydrate
  • Vanadyl pyrophosphate catalysts

Cite this

Rownaghi, Ali Asghar ; Taufiq-Yap, Yun Hin ; Rezaei, Fateme. / Innovative process for the synthesis of vanadyl pyrophosphate as a highly selective catalyst for n-butane oxidation. In: Chemical Engineering Journal. 2010 ; Vol. 165, No. 1. pp. 328-335.
@article{f48df6b8c5cf4f418189c8cdc666c863,
title = "Innovative process for the synthesis of vanadyl pyrophosphate as a highly selective catalyst for n-butane oxidation",
abstract = "Vanadyl pyrophosphate (VPO) catalysts are used for the selective oxidation of light alkanes, which are based on vanadyl hydrogen phosphate hemihydrate (VOHPO4·0.5H2O) as the precursor. Catalyst precursor with well-defined crystal size has been successfully synthesized for the first time, using a simple one-step high-pressure autoclave that was surfactant-free and water-free method with significantly lower temperature and shorter reaction time. VOHPO4·0.5H2O was prepared from V2O5 using an isobutanol, 1-pentanol, 1-heptanol and 1-dectanol as both solvent and reducing agent at elevated temperatures (100, 120, and 150°C). This new method significantly reduced the preparation time and lowered production temperature (50{\%}) of catalyst precursor (VOHPO4·0.5H2O) when compared to conventional hydrothermal synthesis methods. VOHPO4·0.5H2O can be obtained at temperature far below 150°C. It was found that the presence of 1-heptanol and 1-decanol in the reaction mixtures is crucial for obtaining a well-defined crystal size of precursor phase and solely generated impurity [VO(H2PO4)2]. Our findings show that both the phase composition and morphology of vanadium phosphate can be influenced by the use of different reducing agents and temperatures during the preparation process. This new methodology produces catalysts with a much higher surface area (ca. 23m2g-1) compared with those materials prepared by slow hydrothermal synthesis (ca. 9.5m2g-1). Finally, the yield of maleic anhydride was significantly increased from 21.3{\%} for conventional catalyst to 37.9{\%} for the new solvothermal catalyst. ",
keywords = "High-pressure autoclave, N-Butane oxidation, Solvothermal synthesis, Vanadyl hydrogen phosphate hemihydrate, Vanadyl pyrophosphate catalysts",
author = "Rownaghi, {Ali Asghar} and Taufiq-Yap, {Yun Hin} and Fateme Rezaei",
year = "2010",
month = "11",
day = "15",
doi = "10.1016/j.cej.2010.09.043",
language = "English",
volume = "165",
pages = "328--335",
journal = "Chemical Engineering Journal",
issn = "1385-8947",
publisher = "Elsevier",
number = "1",

}

Innovative process for the synthesis of vanadyl pyrophosphate as a highly selective catalyst for n-butane oxidation. / Rownaghi, Ali Asghar; Taufiq-Yap, Yun Hin; Rezaei, Fateme.

In: Chemical Engineering Journal, Vol. 165, No. 1, 15.11.2010, p. 328-335.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Innovative process for the synthesis of vanadyl pyrophosphate as a highly selective catalyst for n-butane oxidation

AU - Rownaghi, Ali Asghar

AU - Taufiq-Yap, Yun Hin

AU - Rezaei, Fateme

PY - 2010/11/15

Y1 - 2010/11/15

N2 - Vanadyl pyrophosphate (VPO) catalysts are used for the selective oxidation of light alkanes, which are based on vanadyl hydrogen phosphate hemihydrate (VOHPO4·0.5H2O) as the precursor. Catalyst precursor with well-defined crystal size has been successfully synthesized for the first time, using a simple one-step high-pressure autoclave that was surfactant-free and water-free method with significantly lower temperature and shorter reaction time. VOHPO4·0.5H2O was prepared from V2O5 using an isobutanol, 1-pentanol, 1-heptanol and 1-dectanol as both solvent and reducing agent at elevated temperatures (100, 120, and 150°C). This new method significantly reduced the preparation time and lowered production temperature (50%) of catalyst precursor (VOHPO4·0.5H2O) when compared to conventional hydrothermal synthesis methods. VOHPO4·0.5H2O can be obtained at temperature far below 150°C. It was found that the presence of 1-heptanol and 1-decanol in the reaction mixtures is crucial for obtaining a well-defined crystal size of precursor phase and solely generated impurity [VO(H2PO4)2]. Our findings show that both the phase composition and morphology of vanadium phosphate can be influenced by the use of different reducing agents and temperatures during the preparation process. This new methodology produces catalysts with a much higher surface area (ca. 23m2g-1) compared with those materials prepared by slow hydrothermal synthesis (ca. 9.5m2g-1). Finally, the yield of maleic anhydride was significantly increased from 21.3% for conventional catalyst to 37.9% for the new solvothermal catalyst. 

AB - Vanadyl pyrophosphate (VPO) catalysts are used for the selective oxidation of light alkanes, which are based on vanadyl hydrogen phosphate hemihydrate (VOHPO4·0.5H2O) as the precursor. Catalyst precursor with well-defined crystal size has been successfully synthesized for the first time, using a simple one-step high-pressure autoclave that was surfactant-free and water-free method with significantly lower temperature and shorter reaction time. VOHPO4·0.5H2O was prepared from V2O5 using an isobutanol, 1-pentanol, 1-heptanol and 1-dectanol as both solvent and reducing agent at elevated temperatures (100, 120, and 150°C). This new method significantly reduced the preparation time and lowered production temperature (50%) of catalyst precursor (VOHPO4·0.5H2O) when compared to conventional hydrothermal synthesis methods. VOHPO4·0.5H2O can be obtained at temperature far below 150°C. It was found that the presence of 1-heptanol and 1-decanol in the reaction mixtures is crucial for obtaining a well-defined crystal size of precursor phase and solely generated impurity [VO(H2PO4)2]. Our findings show that both the phase composition and morphology of vanadium phosphate can be influenced by the use of different reducing agents and temperatures during the preparation process. This new methodology produces catalysts with a much higher surface area (ca. 23m2g-1) compared with those materials prepared by slow hydrothermal synthesis (ca. 9.5m2g-1). Finally, the yield of maleic anhydride was significantly increased from 21.3% for conventional catalyst to 37.9% for the new solvothermal catalyst. 

KW - High-pressure autoclave

KW - N-Butane oxidation

KW - Solvothermal synthesis

KW - Vanadyl hydrogen phosphate hemihydrate

KW - Vanadyl pyrophosphate catalysts

UR - http://www.scopus.com/inward/record.url?scp=78149497895&partnerID=8YFLogxK

U2 - 10.1016/j.cej.2010.09.043

DO - 10.1016/j.cej.2010.09.043

M3 - Article

VL - 165

SP - 328

EP - 335

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

SN - 1385-8947

IS - 1

ER -