Inclusion controlled lanthanide-imidazolium functionalised carboxylate complexation

Irene Ling; Yatimah Alias; Brian W. Skelton; Colin L. Raston

doi:10.1039/c2dt12410f

Inclusion controlled lanthanide-imidazolium functionalised carboxylate complexation

Irene Ling, Yatimah Alias, Brian W. Skelton, Colin L. Raston

Research output: Contribution to journal › Article › Research › peer-review

9 Citations (Scopus)

Abstract

Imidazolium functionalized carboxylic acid forms a multi-component material with p-sulfonatocalix[4]arene and aquated lanthanide ions, stabilising dinuclear metal complexes for Y ³⁺ and Gd ³⁺. These have the simplest binding of two bridging carboxylates between the two metal centres (Y ³⁺), or the same arrangement along with the simplest binding of one carboxylate bridging two metal ions for the larger metal ion (Gd ³⁺).

Original language	English
Pages (from-to)	4884-4889
Number of pages	6
Journal	Dalton Transactions
Volume	41
Issue number	16
DOIs	https://doi.org/10.1039/c2dt12410f
Publication status	Published - 28 Apr 2012
Externally published	Yes

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abstract = "Imidazolium functionalized carboxylic acid forms a multi-component material with p-sulfonatocalix[4]arene and aquated lanthanide ions, stabilising dinuclear metal complexes for Y 3+ and Gd 3+. These have the simplest binding of two bridging carboxylates between the two metal centres (Y 3+), or the same arrangement along with the simplest binding of one carboxylate bridging two metal ions for the larger metal ion (Gd 3+).",

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AU - Alias, Yatimah

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AU - Raston, Colin L.

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AB - Imidazolium functionalized carboxylic acid forms a multi-component material with p-sulfonatocalix[4]arene and aquated lanthanide ions, stabilising dinuclear metal complexes for Y 3+ and Gd 3+. These have the simplest binding of two bridging carboxylates between the two metal centres (Y 3+), or the same arrangement along with the simplest binding of one carboxylate bridging two metal ions for the larger metal ion (Gd 3+).

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Inclusion controlled lanthanide-imidazolium functionalised carboxylate complexation

Abstract

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