Improved syntheses of Ru(CO)2 (O3SCF3)2 (bidentate) complexes and their conversion into new [Ru(CO)2 (bidentate)2]2+ complexes

David St C Black; Glen B. Deacon; Nicholas C. Thomas

doi:10.1016/S0277-5387(00)83938-8

Improved syntheses of Ru(CO)₂ (O₃SCF₃)₂ (bidentate) complexes and their conversion into new [Ru(CO)₂ (bidentate)₂]²⁺ complexes

David St C Black, Glen B. Deacon, Nicholas C. Thomas

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

32 Citations (Scopus)

Abstract

Reaction of the complexes Ru(CO)₂Cl₂L [L = 2,2′-bipyridyl (bpy) or 1,10-phenanthroline (phen)] with trifluoromethanesulphonic acid under carefully controlled conditions yields Ru[cis-(CO)₂] [cis-(O₃SCF₃)₂] (bidentate complexes. From reactions of the trifluoromethanesulphonates with the appropriate bidentate ligands, the new complexes [cis-Ru(CO)₂-L(L′)]²⁺ (L as above; L′ = 4,4′-dimethyl-2,2′-bipyridyl or 4,4′-diisopropyl-2,2′-bipyridyl) as well as the known [_cis-Ru(CO)₂L₂]²⁺ and [cis-Ru(CO)₂bpy(phen)]²⁺ have been prepared.

Original language	English
Pages (from-to)	409-412
Number of pages	4
Journal	Polyhedron
Volume	2
Issue number	5
DOIs	https://doi.org/10.1016/S0277-5387(00)83938-8
Publication status	Published - 1983

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@article{c67ea7f992d34436a039dcdf398a139d,

title = "Improved syntheses of Ru(CO)2 (O3SCF3)2 (bidentate) complexes and their conversion into new [Ru(CO)2 (bidentate)2]2+ complexes",

abstract = "Reaction of the complexes Ru(CO)2Cl2L [L = 2,2′-bipyridyl (bpy) or 1,10-phenanthroline (phen)] with trifluoromethanesulphonic acid under carefully controlled conditions yields Ru[cis-(CO)2] [cis-(O3SCF3)2] (bidentate complexes. From reactions of the trifluoromethanesulphonates with the appropriate bidentate ligands, the new complexes [cis-Ru(CO)2-L(L′)]2+ (L as above; L′ = 4,4′-dimethyl-2,2′-bipyridyl or 4,4′-diisopropyl-2,2′-bipyridyl) as well as the known [cis-Ru(CO)2L2]2+ and [cis-Ru(CO)2bpy(phen)]2+ have been prepared. ",

author = "Black, {David St C} and Deacon, {Glen B.} and Thomas, {Nicholas C.}",

year = "1983",

doi = "10.1016/S0277-5387(00)83938-8",

language = "English",

volume = "2",

pages = "409--412",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "5",

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TY - JOUR

T1 - Improved syntheses of Ru(CO)2 (O3SCF3)2 (bidentate) complexes and their conversion into new [Ru(CO)2 (bidentate)2]2+ complexes

AU - Black, David St C

AU - Deacon, Glen B.

AU - Thomas, Nicholas C.

PY - 1983

Y1 - 1983

N2 - Reaction of the complexes Ru(CO)2Cl2L [L = 2,2′-bipyridyl (bpy) or 1,10-phenanthroline (phen)] with trifluoromethanesulphonic acid under carefully controlled conditions yields Ru[cis-(CO)2] [cis-(O3SCF3)2] (bidentate complexes. From reactions of the trifluoromethanesulphonates with the appropriate bidentate ligands, the new complexes [cis-Ru(CO)2-L(L′)]2+ (L as above; L′ = 4,4′-dimethyl-2,2′-bipyridyl or 4,4′-diisopropyl-2,2′-bipyridyl) as well as the known [cis-Ru(CO)2L2]2+ and [cis-Ru(CO)2bpy(phen)]2+ have been prepared.

AB - Reaction of the complexes Ru(CO)2Cl2L [L = 2,2′-bipyridyl (bpy) or 1,10-phenanthroline (phen)] with trifluoromethanesulphonic acid under carefully controlled conditions yields Ru[cis-(CO)2] [cis-(O3SCF3)2] (bidentate complexes. From reactions of the trifluoromethanesulphonates with the appropriate bidentate ligands, the new complexes [cis-Ru(CO)2-L(L′)]2+ (L as above; L′ = 4,4′-dimethyl-2,2′-bipyridyl or 4,4′-diisopropyl-2,2′-bipyridyl) as well as the known [cis-Ru(CO)2L2]2+ and [cis-Ru(CO)2bpy(phen)]2+ have been prepared.

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U2 - 10.1016/S0277-5387(00)83938-8

DO - 10.1016/S0277-5387(00)83938-8

M3 - Article

AN - SCOPUS:0011203565

SN - 0277-5387

VL - 2

SP - 409

EP - 412

JO - Polyhedron

JF - Polyhedron

IS - 5

ER -

Improved syntheses of Ru(CO)2 (O3SCF3)2 (bidentate) complexes and their conversion into new [Ru(CO)2 (bidentate)2]2+ complexes

Abstract

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Improved syntheses of Ru(CO)₂ (O₃SCF₃)₂ (bidentate) complexes and their conversion into new [Ru(CO)₂ (bidentate)₂]²⁺ complexes