Hysteretic spin crossover driven by anion conformational change

Natnaree Phukkaphan; Dyanne L. Cruickshank; Keith S. Murray; Wasinee Phonsri; Phimphaka Harding; David J. Harding

doi:10.1039/c7cc05998a

Hysteretic spin crossover driven by anion conformational change

Natnaree Phukkaphan, Dyanne L. Cruickshank, Keith S. Murray, Wasinee Phonsri, Phimphaka Harding, David J. Harding

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

46 Citations (Scopus)

Abstract

A new air stable Fe^III spin crossover (SCO) complex has been synthesized. The compound undergoes abrupt SCO near room temperature with T_1/2 (↓) = 244 K and T_1/2 (↑) = 278 K. Structural studies of the complex in the high spin and low spin state show that the strong cooperativity and thus the wide hysteresis is driven by an unprecedented anionic conformational change.

Original language	English
Pages (from-to)	9801-9804
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	70
DOIs	https://doi.org/10.1039/c7cc05998a
Publication status	Published - 1 Jan 2017

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abstract = "A new air stable FeIII spin crossover (SCO) complex has been synthesized. The compound undergoes abrupt SCO near room temperature with T1/2 (↓) = 244 K and T1/2 (↑) = 278 K. Structural studies of the complex in the high spin and low spin state show that the strong cooperativity and thus the wide hysteresis is driven by an unprecedented anionic conformational change.",

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AU - Cruickshank, Dyanne L.

AU - Murray, Keith S.

AU - Phonsri, Wasinee

AU - Harding, Phimphaka

AU - Harding, David J.

PY - 2017/1/1

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N2 - A new air stable FeIII spin crossover (SCO) complex has been synthesized. The compound undergoes abrupt SCO near room temperature with T1/2 (↓) = 244 K and T1/2 (↑) = 278 K. Structural studies of the complex in the high spin and low spin state show that the strong cooperativity and thus the wide hysteresis is driven by an unprecedented anionic conformational change.

AB - A new air stable FeIII spin crossover (SCO) complex has been synthesized. The compound undergoes abrupt SCO near room temperature with T1/2 (↓) = 244 K and T1/2 (↑) = 278 K. Structural studies of the complex in the high spin and low spin state show that the strong cooperativity and thus the wide hysteresis is driven by an unprecedented anionic conformational change.

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VL - 53

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EP - 9804

JO - Chemical Communications

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Hysteretic spin crossover driven by anion conformational change

Abstract

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