Hyperfine interactions in methanimine

Ronald Brown, Peter Godfrey, David Winkler

Research output: Contribution to journalArticleResearchpeer-review

16 Citations (Scopus)

Abstract

A high-resolution study of hyperfine splitting in the microwave spectrum of methanimine has yielded the following values (in MHz) for 14N hyperfine constants: χaa -0·898(8), χbb -2·693(8), χcc 3·591(8), Ca -0·0495(47), Cb -0·0097(27), Cc -0·0012(24). The localized theory for calculation of the magnetic hyperfine constants appears generally to overestimate Cc by an order of magnitude for molecules structurally similar to methanimine.
Original languageEnglish
Pages (from-to)667-672
Number of pages6
JournalAustralian Journal of Chemistry
Volume35
Issue number4
DOIs
Publication statusPublished - 1982

Cite this

Brown, Ronald ; Godfrey, Peter ; Winkler, David. / Hyperfine interactions in methanimine. In: Australian Journal of Chemistry. 1982 ; Vol. 35, No. 4. pp. 667-672.
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Brown, R, Godfrey, P & Winkler, D 1982, 'Hyperfine interactions in methanimine', Australian Journal of Chemistry, vol. 35, no. 4, pp. 667-672. https://doi.org/10.1071/CH9820667

Hyperfine interactions in methanimine. / Brown, Ronald; Godfrey, Peter; Winkler, David.

In: Australian Journal of Chemistry, Vol. 35, No. 4, 1982, p. 667-672.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Hyperfine interactions in methanimine

AU - Brown, Ronald

AU - Godfrey, Peter

AU - Winkler, David

PY - 1982

Y1 - 1982

N2 - A high-resolution study of hyperfine splitting in the microwave spectrum of methanimine has yielded the following values (in MHz) for 14N hyperfine constants: χaa -0·898(8), χbb -2·693(8), χcc 3·591(8), Ca -0·0495(47), Cb -0·0097(27), Cc -0·0012(24). The localized theory for calculation of the magnetic hyperfine constants appears generally to overestimate Cc by an order of magnitude for molecules structurally similar to methanimine.

AB - A high-resolution study of hyperfine splitting in the microwave spectrum of methanimine has yielded the following values (in MHz) for 14N hyperfine constants: χaa -0·898(8), χbb -2·693(8), χcc 3·591(8), Ca -0·0495(47), Cb -0·0097(27), Cc -0·0012(24). The localized theory for calculation of the magnetic hyperfine constants appears generally to overestimate Cc by an order of magnitude for molecules structurally similar to methanimine.

U2 - 10.1071/CH9820667

DO - 10.1071/CH9820667

M3 - Article

VL - 35

SP - 667

EP - 672

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

SN - 0004-9425

IS - 4

ER -