Hydrothermal synthesis of polyaniline-iron oxide nano-composite materials

Hong-Ying Liu, Shuang-Bao Wang, Ying Zhu, Lei Jiang

Research output: Contribution to journalArticleResearchpeer-review

1 Citation (Scopus)

Abstract

Polyaniline nanomaterials and its iron oxide nanocomposites were fabricated by combining hydrothermal synthesis and template-free polymerization method. The morphology and composition of as-synthesized composites can be controlled by changing the concentration of ferric chloride, which act as oxidant, dopant and reactant at the same time in process of polymerization. When the concentration of ferric chloride is lower than 0.13 mol/L, the composition of the product are eigenstates polyaniline and α-Fe2O3 nanocomposites, the morphology of the product are sub-microscale quasi-cube self-assembled by nanoparticles; If the concentration of ferric chloride increased to 0.20 mol/L, the composition of the product changed to doped polyaniline nanomaterial, the morphology of the as-synthesized changed to dahlia-like microsphere self-assembled by nanolamellar structure. And the diameter of products increases with the increase of ferric chloride. By means of SEM, FTIR, UV-Vis, XPS and XRD, microstructure and composition of the products were characterized, and formation mechanism are also addressed.

Original languageEnglish
Pages (from-to)1303-1308
Number of pages6
JournalGaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume34
Issue number5
DOIs
Publication statusPublished - May 2013
Externally publishedYes

Keywords

  • Hydrothermal method
  • Iron oxide
  • Nano-composite material
  • Polyaniline

Cite this

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title = "Hydrothermal synthesis of polyaniline-iron oxide nano-composite materials",
abstract = "Polyaniline nanomaterials and its iron oxide nanocomposites were fabricated by combining hydrothermal synthesis and template-free polymerization method. The morphology and composition of as-synthesized composites can be controlled by changing the concentration of ferric chloride, which act as oxidant, dopant and reactant at the same time in process of polymerization. When the concentration of ferric chloride is lower than 0.13 mol/L, the composition of the product are eigenstates polyaniline and α-Fe2O3 nanocomposites, the morphology of the product are sub-microscale quasi-cube self-assembled by nanoparticles; If the concentration of ferric chloride increased to 0.20 mol/L, the composition of the product changed to doped polyaniline nanomaterial, the morphology of the as-synthesized changed to dahlia-like microsphere self-assembled by nanolamellar structure. And the diameter of products increases with the increase of ferric chloride. By means of SEM, FTIR, UV-Vis, XPS and XRD, microstructure and composition of the products were characterized, and formation mechanism are also addressed.",
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Hydrothermal synthesis of polyaniline-iron oxide nano-composite materials. / Liu, Hong-Ying; Wang, Shuang-Bao; Zhu, Ying; Jiang, Lei.

In: Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities, Vol. 34, No. 5, 05.2013, p. 1303-1308.

Research output: Contribution to journalArticleResearchpeer-review

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AB - Polyaniline nanomaterials and its iron oxide nanocomposites were fabricated by combining hydrothermal synthesis and template-free polymerization method. The morphology and composition of as-synthesized composites can be controlled by changing the concentration of ferric chloride, which act as oxidant, dopant and reactant at the same time in process of polymerization. When the concentration of ferric chloride is lower than 0.13 mol/L, the composition of the product are eigenstates polyaniline and α-Fe2O3 nanocomposites, the morphology of the product are sub-microscale quasi-cube self-assembled by nanoparticles; If the concentration of ferric chloride increased to 0.20 mol/L, the composition of the product changed to doped polyaniline nanomaterial, the morphology of the as-synthesized changed to dahlia-like microsphere self-assembled by nanolamellar structure. And the diameter of products increases with the increase of ferric chloride. By means of SEM, FTIR, UV-Vis, XPS and XRD, microstructure and composition of the products were characterized, and formation mechanism are also addressed.

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