Hydrothermal synthesis of dioctahedral smectites: The Al-Fe3+ chemical series. Part II: Crystal-chemistry

Sabine Petit, Alain Decarreau, Will Peter Gates, Pauline Andrieux, Olivier Grauby

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The crystal-chemistry of a series of synthetic Al-Fe3+ smectites was studied in detail using near and mid infrared spectroscopy. Chemical and NIR data indicated a quite complete range of octahedral Al for Fe3+ substitution, and therefore, the solid-solution between beidellite and nontronite end-members was continuous and complete. The wavenumbers of several infrared absorption bands were correlated with the chemistry of the synthetic smectites, providing a useful tool to constrain their structural formulae and also for assisting in assignments of similar bands in natural smectites. The Al and Fe3+ cations were shown to be randomly distributed in the octahedral sheet of synthesized smectites. Despite the high availability of iron during synthesis, generally only a small amount of tetrahedral Fe3+ was observed.
Original languageEnglish
Pages (from-to)96 - 105
Number of pages10
JournalApplied Clay Science
Publication statusPublished - Feb 2015


  • Nontronite
  • Near infrared
  • Fe-beidellite
  • Synthesis

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