Hybridizing TiO2 with nitrogen-doped carbon: A new route to a highly visible light-active photocatalyst

Xiaofang Chen, Zongli Xie, Yan Liang, Jing Wei, Yonggang Zhu, Yuning Huo, Xiwang Zhang, Huanting Wang

Research output: Contribution to journalArticleResearchpeer-review

Abstract

TiO2 hybridized with nitrogen-doped carbon (N-doped C/TiO2) was prepared as a photocatalyst with improved visible-light catalytic activity for the first time. It was found that N-doped carbon was formed by etching and partial decomposition of as-formed graphitic carbon nitride on the surface of TiO2 under calcination at 500 °C in open air, which avoided direct doping of nitrogen into TiO2 structure. N-doped carbon on the surface of TiO2 led to an enhanced light absorption in the range of 400 to 550 nm. The resulting N-doped C/TiO2 exhibited about 2 times higher activity than the graphitic carbon nitride/TiO2 prepared by direct carbonization in argon atmosphere. Compared with the commercial TiO2 (Degussa, P25), N-doped C/TiO2 showed a higher reaction rate in the degradation of various pollutants such as rhodamine B, phenol and methyl orange (MO) under simulated solar light irradiation.

Original languageEnglish
Pages (from-to)1565-1572
Number of pages8
JournalChemistrySelect
Volume2
Issue number4
DOIs
Publication statusPublished - 1 Jan 2017

Keywords

  • Composite
  • Nitrogen-doped carbon
  • Organic pollutants
  • Photocatalysis
  • TiO

Cite this

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title = "Hybridizing TiO2 with nitrogen-doped carbon: A new route to a highly visible light-active photocatalyst",
abstract = "TiO2 hybridized with nitrogen-doped carbon (N-doped C/TiO2) was prepared as a photocatalyst with improved visible-light catalytic activity for the first time. It was found that N-doped carbon was formed by etching and partial decomposition of as-formed graphitic carbon nitride on the surface of TiO2 under calcination at 500 °C in open air, which avoided direct doping of nitrogen into TiO2 structure. N-doped carbon on the surface of TiO2 led to an enhanced light absorption in the range of 400 to 550 nm. The resulting N-doped C/TiO2 exhibited about 2 times higher activity than the graphitic carbon nitride/TiO2 prepared by direct carbonization in argon atmosphere. Compared with the commercial TiO2 (Degussa, P25), N-doped C/TiO2 showed a higher reaction rate in the degradation of various pollutants such as rhodamine B, phenol and methyl orange (MO) under simulated solar light irradiation.",
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Hybridizing TiO2 with nitrogen-doped carbon : A new route to a highly visible light-active photocatalyst. / Chen, Xiaofang; Xie, Zongli; Liang, Yan; Wei, Jing; Zhu, Yonggang; Huo, Yuning; Zhang, Xiwang; Wang, Huanting.

In: ChemistrySelect, Vol. 2, No. 4, 01.01.2017, p. 1565-1572.

Research output: Contribution to journalArticleResearchpeer-review

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T2 - A new route to a highly visible light-active photocatalyst

AU - Chen, Xiaofang

AU - Xie, Zongli

AU - Liang, Yan

AU - Wei, Jing

AU - Zhu, Yonggang

AU - Huo, Yuning

AU - Zhang, Xiwang

AU - Wang, Huanting

PY - 2017/1/1

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N2 - TiO2 hybridized with nitrogen-doped carbon (N-doped C/TiO2) was prepared as a photocatalyst with improved visible-light catalytic activity for the first time. It was found that N-doped carbon was formed by etching and partial decomposition of as-formed graphitic carbon nitride on the surface of TiO2 under calcination at 500 °C in open air, which avoided direct doping of nitrogen into TiO2 structure. N-doped carbon on the surface of TiO2 led to an enhanced light absorption in the range of 400 to 550 nm. The resulting N-doped C/TiO2 exhibited about 2 times higher activity than the graphitic carbon nitride/TiO2 prepared by direct carbonization in argon atmosphere. Compared with the commercial TiO2 (Degussa, P25), N-doped C/TiO2 showed a higher reaction rate in the degradation of various pollutants such as rhodamine B, phenol and methyl orange (MO) under simulated solar light irradiation.

AB - TiO2 hybridized with nitrogen-doped carbon (N-doped C/TiO2) was prepared as a photocatalyst with improved visible-light catalytic activity for the first time. It was found that N-doped carbon was formed by etching and partial decomposition of as-formed graphitic carbon nitride on the surface of TiO2 under calcination at 500 °C in open air, which avoided direct doping of nitrogen into TiO2 structure. N-doped carbon on the surface of TiO2 led to an enhanced light absorption in the range of 400 to 550 nm. The resulting N-doped C/TiO2 exhibited about 2 times higher activity than the graphitic carbon nitride/TiO2 prepared by direct carbonization in argon atmosphere. Compared with the commercial TiO2 (Degussa, P25), N-doped C/TiO2 showed a higher reaction rate in the degradation of various pollutants such as rhodamine B, phenol and methyl orange (MO) under simulated solar light irradiation.

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