Humic acids and methylated humic acids as models for reactions of brown coal with CO/H2O and with H2

L. M. Clemow; G. Favas; W. R. Jackson; M. Marshall; A. F. Patti; P. J. Redlich

doi:10.1016/S0016-2361(98)00184-7

Humic acids and methylated humic acids as models for reactions of brown coal with CO/H₂O and with H₂

L. M. Clemow, G. Favas, W. R. Jackson, M. Marshall, A. F. Patti, P. J. Redlich

Research output: Contribution to journal › Article › Research › peer-review

13 Citations (Scopus)

Abstract

Humic acid and its mild O-methylation product were reacted first with CO/H₂O/NaAlO₂ and H₂/Ni/Mo in 35 ml autoclaves at 365°C and 400°C. Reaction was also made with H₂/MeOH both with and without added ZnCl₂ catalyst. A comparison of the results of this study with that of Kuznetsov et al. confirmed that the autoclave constitutes a well-mixed system and that the H₂MeOH/ZnCl₂ system more closely resembles the H₂/Ni/Mo rather than the CO/H₂O/NaAlO₂ system.

Original language	English
Pages (from-to)	567-572
Number of pages	6
Journal	Fuel
Volume	78
Issue number	5
DOIs	https://doi.org/10.1016/S0016-2361(98)00184-7
Publication status	Published - 1 Jan 1999

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title = "Humic acids and methylated humic acids as models for reactions of brown coal with CO/H2O and with H2",

abstract = "Humic acid and its mild O-methylation product were reacted first with CO/H2O/NaAlO2 and H2/Ni/Mo in 35 ml autoclaves at 365°C and 400°C. Reaction was also made with H2/MeOH both with and without added ZnCl2 catalyst. A comparison of the results of this study with that of Kuznetsov et al. confirmed that the autoclave constitutes a well-mixed system and that the H2MeOH/ZnCl2 system more closely resembles the H2/Ni/Mo rather than the CO/H2O/NaAlO2 system.",

author = "Clemow, {L. M.} and G. Favas and Jackson, {W. R.} and M. Marshall and Patti, {A. F.} and Redlich, {P. J.}",

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T1 - Humic acids and methylated humic acids as models for reactions of brown coal with CO/H2O and with H2

AU - Clemow, L. M.

AU - Favas, G.

AU - Jackson, W. R.

AU - Marshall, M.

AU - Patti, A. F.

AU - Redlich, P. J.

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Humic acid and its mild O-methylation product were reacted first with CO/H2O/NaAlO2 and H2/Ni/Mo in 35 ml autoclaves at 365°C and 400°C. Reaction was also made with H2/MeOH both with and without added ZnCl2 catalyst. A comparison of the results of this study with that of Kuznetsov et al. confirmed that the autoclave constitutes a well-mixed system and that the H2MeOH/ZnCl2 system more closely resembles the H2/Ni/Mo rather than the CO/H2O/NaAlO2 system.

AB - Humic acid and its mild O-methylation product were reacted first with CO/H2O/NaAlO2 and H2/Ni/Mo in 35 ml autoclaves at 365°C and 400°C. Reaction was also made with H2/MeOH both with and without added ZnCl2 catalyst. A comparison of the results of this study with that of Kuznetsov et al. confirmed that the autoclave constitutes a well-mixed system and that the H2MeOH/ZnCl2 system more closely resembles the H2/Ni/Mo rather than the CO/H2O/NaAlO2 system.

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DO - 10.1016/S0016-2361(98)00184-7

M3 - Article

AN - SCOPUS:0033301008

SN - 0016-2361

VL - 78

SP - 567

EP - 572

JO - Fuel

JF - Fuel

IS - 5

ER -

Humic acids and methylated humic acids as models for reactions of brown coal with CO/H2O and with H2

Abstract

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Humic acids and methylated humic acids as models for reactions of brown coal with CO/H₂O and with H₂