Highly selective ammonia synthesis from nitrate with photocatalytically generated hydrogen on CuPd/TiO2

Miho Yamauchi; Ryu Abe; Tatsuya Tsukuda; Kenichi Kato; Masaki Takata

doi:10.1021/ja106285p

Highly selective ammonia synthesis from nitrate with photocatalytically generated hydrogen on CuPd/TiO₂

Miho Yamauchi, Ryu Abe, Tatsuya Tsukuda, Kenichi Kato, Masaki Takata

Research output: Contribution to journal › Article › Research › peer-review

122 Citations (Scopus)

Abstract

Body-centered-cubic type CuPd nanoalloys were synthesized by a chemical reduction method. Photocatalytic hydrogen evolution and nitrate reduction were simultaneously examined over CuPd nanoalloys deposited on TiO₂ (CuPd/TiO₂). The efficiency of hydrogen evolution over CuPd/TiO ₂ was better than that over Pd/TiO₂. As for nitrate reduction, ammonia was selectively (78%) produced with hydrogen generated photocatalytically over CuPd/TiO₂. The continuous generation of nascent hydrogen atoms on the surface of the CuPd nanoalloy, where Cu and Pd are homogeneously mixed, led to the high selectivity for ammonia.

Original language	English
Pages (from-to)	1150-1152
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	133
Issue number	5
DOIs	https://doi.org/10.1021/ja106285p
Publication status	Published - 9 Feb 2011
Externally published	Yes

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title = "Highly selective ammonia synthesis from nitrate with photocatalytically generated hydrogen on CuPd/TiO2",

abstract = "Body-centered-cubic type CuPd nanoalloys were synthesized by a chemical reduction method. Photocatalytic hydrogen evolution and nitrate reduction were simultaneously examined over CuPd nanoalloys deposited on TiO2 (CuPd/TiO2). The efficiency of hydrogen evolution over CuPd/TiO 2 was better than that over Pd/TiO2. As for nitrate reduction, ammonia was selectively (78\%) produced with hydrogen generated photocatalytically over CuPd/TiO2. The continuous generation of nascent hydrogen atoms on the surface of the CuPd nanoalloy, where Cu and Pd are homogeneously mixed, led to the high selectivity for ammonia.",

author = "Miho Yamauchi and Ryu Abe and Tatsuya Tsukuda and Kenichi Kato and Masaki Takata",

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T1 - Highly selective ammonia synthesis from nitrate with photocatalytically generated hydrogen on CuPd/TiO2

AU - Yamauchi, Miho

AU - Abe, Ryu

AU - Tsukuda, Tatsuya

AU - Kato, Kenichi

AU - Takata, Masaki

PY - 2011/2/9

Y1 - 2011/2/9

N2 - Body-centered-cubic type CuPd nanoalloys were synthesized by a chemical reduction method. Photocatalytic hydrogen evolution and nitrate reduction were simultaneously examined over CuPd nanoalloys deposited on TiO2 (CuPd/TiO2). The efficiency of hydrogen evolution over CuPd/TiO 2 was better than that over Pd/TiO2. As for nitrate reduction, ammonia was selectively (78%) produced with hydrogen generated photocatalytically over CuPd/TiO2. The continuous generation of nascent hydrogen atoms on the surface of the CuPd nanoalloy, where Cu and Pd are homogeneously mixed, led to the high selectivity for ammonia.

AB - Body-centered-cubic type CuPd nanoalloys were synthesized by a chemical reduction method. Photocatalytic hydrogen evolution and nitrate reduction were simultaneously examined over CuPd nanoalloys deposited on TiO2 (CuPd/TiO2). The efficiency of hydrogen evolution over CuPd/TiO 2 was better than that over Pd/TiO2. As for nitrate reduction, ammonia was selectively (78%) produced with hydrogen generated photocatalytically over CuPd/TiO2. The continuous generation of nascent hydrogen atoms on the surface of the CuPd nanoalloy, where Cu and Pd are homogeneously mixed, led to the high selectivity for ammonia.

UR - https://www.scopus.com/pages/publications/79551692300

U2 - 10.1021/ja106285p

DO - 10.1021/ja106285p

M3 - Article

AN - SCOPUS:79551692300

SN - 0002-7863

VL - 133

SP - 1150

EP - 1152

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 5

ER -

Highly selective ammonia synthesis from nitrate with photocatalytically generated hydrogen on CuPd/TiO2

Abstract

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Highly selective ammonia synthesis from nitrate with photocatalytically generated hydrogen on CuPd/TiO₂