Highly reactive carbenes as ligands for main group element fluorides. Syntheses and applications

Tobias Bottcher; Gerd-Volker Roschenthaler

doi:10.1016/j.jfluchem.2014.10.018

Highly reactive carbenes as ligands for main group element fluorides. Syntheses and applications

Tobias Bottcher, Gerd-Volker Roschenthaler

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

Abstract

In this review carbene complexes of main group fluorides are summarized. So far, the vast majority of those complexes were obtained by 1:1 addition reactions using free carbene. In 2012, the utilization of 2,2-difluoro-1,3-dimethylimidazolidine (DFI) and analogs were reported as carbene sources for main group fluorides. Further studies demonstrated the versatility of this procedure and allowed the straightforward synthesis of new classes of compounds which otherwise could not be obtained via the free carbene route. Furthermore, examples of functionalized materials based on carbene complexes of phosphorus(V) fluorides are summarized here as well

Original language	English
Pages (from-to)	4-11
Number of pages	8
Journal	Journal of Fluorine Chemistry
Volume	171
DOIs	https://doi.org/10.1016/j.jfluchem.2014.10.018
Publication status	Published - 2015

Keywords

Nitrogen containing carbenes
Adducts
Main group fluorides
Applications

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10.1016/j.jfluchem.2014.10.018

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abstract = "In this review carbene complexes of main group fluorides are summarized. So far, the vast majority of those complexes were obtained by 1:1 addition reactions using free carbene. In 2012, the utilization of 2,2-difluoro-1,3-dimethylimidazolidine (DFI) and analogs were reported as carbene sources for main group fluorides. Further studies demonstrated the versatility of this procedure and allowed the straightforward synthesis of new classes of compounds which otherwise could not be obtained via the free carbene route. Furthermore, examples of functionalized materials based on carbene complexes of phosphorus(V) fluorides are summarized here as well",

keywords = "Nitrogen containing carbenes, Adducts, Main group fluorides, Applications",

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AB - In this review carbene complexes of main group fluorides are summarized. So far, the vast majority of those complexes were obtained by 1:1 addition reactions using free carbene. In 2012, the utilization of 2,2-difluoro-1,3-dimethylimidazolidine (DFI) and analogs were reported as carbene sources for main group fluorides. Further studies demonstrated the versatility of this procedure and allowed the straightforward synthesis of new classes of compounds which otherwise could not be obtained via the free carbene route. Furthermore, examples of functionalized materials based on carbene complexes of phosphorus(V) fluorides are summarized here as well

KW - Nitrogen containing carbenes

KW - Adducts

KW - Main group fluorides

KW - Applications

UR - http://goo.gl/CJJBdp

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DO - 10.1016/j.jfluchem.2014.10.018

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VL - 171

SP - 4

EP - 11

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

ER -

Highly reactive carbenes as ligands for main group element fluorides. Syntheses and applications

Abstract

Keywords

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