Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction

Reihaneh Kardanpour; Shahram Tangestaninejad; Valiollah Mirkhani; Majid Moghadam; Iraj Mohammadpoor-Baltork; Ahmad R. Khosropour; Farnaz Zadehahmadi

doi:10.1016/j.jorganchem.2014.03.012

Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction

Reihaneh Kardanpour
, Shahram Tangestaninejad
, Valiollah Mirkhani
, Majid Moghadam
, Iraj Mohammadpoor-Baltork
, Ahmad R. Khosropour
, Farnaz Zadehahmadi

Research output: Contribution to journal › Article › Research › peer-review

95 Citations (Scopus)

Abstract

Palladium nanoparticles (Pd NPs) supported on amino functionalized UiO-66-NH₂ (UiO = University of Oslo) metal-organic framework was prepared using a direct anionic exchange method followed by chemical reduction with sodium acetate in methanol. This nano palladium containing catalyst was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), N₂ adsorption, inductively coupled plasma atomic emission spectroscopy (ICP-AES), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The Pd/UiO-66-NH₂ catalyst showed excellent activity in Suzuki-Miyaura cross-coupling reaction and reused several times without any appreciable loss of activity even after five consecutive times.

Original language	English
Pages (from-to)	127-133
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	761
DOIs	https://doi.org/10.1016/j.jorganchem.2014.03.012
Publication status	Published - 1 Jul 2014
Externally published	Yes

Keywords

Metal-organic framework
Palladium nanoparticle
Suzuki-Miyaura cross-coupling reaction

Access to Document

10.1016/j.jorganchem.2014.03.012

Cite this

Kardanpour, R., Tangestaninejad, S., Mirkhani, V., Moghadam, M., Mohammadpoor-Baltork, I., Khosropour, A. R., & Zadehahmadi, F. (2014). Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction. Journal of Organometallic Chemistry, 761, 127-133. https://doi.org/10.1016/j.jorganchem.2014.03.012

@article{32102903ad4d4ff09fba2c320ee77735,

title = "Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction",

abstract = "Palladium nanoparticles (Pd NPs) supported on amino functionalized UiO-66-NH2 (UiO = University of Oslo) metal-organic framework was prepared using a direct anionic exchange method followed by chemical reduction with sodium acetate in methanol. This nano palladium containing catalyst was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), N2 adsorption, inductively coupled plasma atomic emission spectroscopy (ICP-AES), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The Pd/UiO-66-NH2 catalyst showed excellent activity in Suzuki-Miyaura cross-coupling reaction and reused several times without any appreciable loss of activity even after five consecutive times.",

keywords = "Metal-organic framework, Palladium nanoparticle, Suzuki-Miyaura cross-coupling reaction",

author = "Reihaneh Kardanpour and Shahram Tangestaninejad and Valiollah Mirkhani and Majid Moghadam and Iraj Mohammadpoor-Baltork and Khosropour, \{Ahmad R.\} and Farnaz Zadehahmadi",

note = "Funding Information: We are thankful to the University of Isfahan for financial support of this work.",

year = "2014",

month = jul,

day = "1",

doi = "10.1016/j.jorganchem.2014.03.012",

language = "English",

volume = "761",

pages = "127--133",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier BV",

}

Kardanpour, R, Tangestaninejad, S, Mirkhani, V, Moghadam, M, Mohammadpoor-Baltork, I, Khosropour, AR & Zadehahmadi, F 2014, 'Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction', Journal of Organometallic Chemistry, vol. 761, pp. 127-133. https://doi.org/10.1016/j.jorganchem.2014.03.012

Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction. / Kardanpour, Reihaneh; Tangestaninejad, Shahram; Mirkhani, Valiollah et al.
In: Journal of Organometallic Chemistry, Vol. 761, 01.07.2014, p. 127-133.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction

AU - Kardanpour, Reihaneh

AU - Tangestaninejad, Shahram

AU - Mirkhani, Valiollah

AU - Moghadam, Majid

AU - Mohammadpoor-Baltork, Iraj

AU - Khosropour, Ahmad R.

AU - Zadehahmadi, Farnaz

N1 - Funding Information: We are thankful to the University of Isfahan for financial support of this work.

PY - 2014/7/1

Y1 - 2014/7/1

N2 - Palladium nanoparticles (Pd NPs) supported on amino functionalized UiO-66-NH2 (UiO = University of Oslo) metal-organic framework was prepared using a direct anionic exchange method followed by chemical reduction with sodium acetate in methanol. This nano palladium containing catalyst was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), N2 adsorption, inductively coupled plasma atomic emission spectroscopy (ICP-AES), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The Pd/UiO-66-NH2 catalyst showed excellent activity in Suzuki-Miyaura cross-coupling reaction and reused several times without any appreciable loss of activity even after five consecutive times.

AB - Palladium nanoparticles (Pd NPs) supported on amino functionalized UiO-66-NH2 (UiO = University of Oslo) metal-organic framework was prepared using a direct anionic exchange method followed by chemical reduction with sodium acetate in methanol. This nano palladium containing catalyst was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), N2 adsorption, inductively coupled plasma atomic emission spectroscopy (ICP-AES), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The Pd/UiO-66-NH2 catalyst showed excellent activity in Suzuki-Miyaura cross-coupling reaction and reused several times without any appreciable loss of activity even after five consecutive times.

KW - Metal-organic framework

KW - Palladium nanoparticle

KW - Suzuki-Miyaura cross-coupling reaction

UR - https://www.scopus.com/pages/publications/84902205462

U2 - 10.1016/j.jorganchem.2014.03.012

DO - 10.1016/j.jorganchem.2014.03.012

M3 - Article

AN - SCOPUS:84902205462

SN - 0022-328X

VL - 761

SP - 127

EP - 133

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Kardanpour R, Tangestaninejad S, Mirkhani V, Moghadam M, Mohammadpoor-Baltork I, Khosropour AR et al. Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction. Journal of Organometallic Chemistry. 2014 Jul 1;761:127-133. doi: 10.1016/j.jorganchem.2014.03.012

Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction

Abstract

Keywords

Access to Document

Other files and links

Cite this