High-resolution FTIR spectroscopy of the v7 and v8 bands of 1-phosphapropyne

Michael Kenneth Bane, Cameron Jones, Sam Lim Choong, Christopher David Thompson, Peter Douglas Godfrey, Dominique R T Appadoo, Donald McNaughton

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Abstract

1-Phosphapropyne has been prepared and high-resolution (0.001 cm-1) spectra have been recorded on the far-infrared beamline at the Australian synchrotron between 1500-700 cm-1 and 400-50 cm-1. Ro-vibrational transitions of the v8 (308 cm-1) and v7 (1006 cm-1) fundamentals as well as the and hot-bands have been assigned, and rotational, centrifugal distortion and Coriolis interaction parameters determined. The hot-band is an example of a particularly complex E
Original languageEnglish
Pages (from-to)9 - 14
Number of pages6
JournalJournal of Molecular Spectroscopy
Volume275
DOIs
Publication statusPublished - 2012

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