Heterogeneous dehalogenation of arylhalides in the presence of ionic liquids

Christian Andre Ohlin; Zoltan Beni; Gabor Laurenczy; Nuria Ruiz; Anna Masdeu-Bulto

doi:10.1002/aoc.1194

Heterogeneous dehalogenation of arylhalides in the presence of ionic liquids

Christian Andre Ohlin, Zoltan Beni, Gabor Laurenczy, Nuria Ruiz, Anna Masdeu-Bulto

Research output: Contribution to journal › Article › Research › peer-review

13 Citations (Scopus)

Abstract

Dehydrohalogenation of haloaromatics in ionic liquids derived from ethylmethylimidazolium or similar salts has been performed using Pd-C, Pd(OAc)(2) and other catalysts using formate salts as a hydrogen source. In the ionic liquid [emim][BF4], chlorobenzene was dehalogenated by up to 40 , bromobenzene up to 25 and iodobenzene up to 41 in 2 h. Reactions in the absence of the ionic liquid were also performed

Original language	English
Pages (from-to)	156 - 160
Number of pages	5
Journal	Applied Organometallic Chemistry
Volume	21
Issue number	3
DOIs	https://doi.org/10.1002/aoc.1194
Publication status	Published - 2007
Externally published	Yes

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abstract = "Dehydrohalogenation of haloaromatics in ionic liquids derived from ethylmethylimidazolium or similar salts has been performed using Pd-C, Pd(OAc)(2) and other catalysts using formate salts as a hydrogen source. In the ionic liquid [emim][BF4], chlorobenzene was dehalogenated by up to 40 , bromobenzene up to 25 and iodobenzene up to 41 in 2 h. Reactions in the absence of the ionic liquid were also performed",

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AU - Ohlin, Christian Andre

AU - Beni, Zoltan

AU - Laurenczy, Gabor

AU - Ruiz, Nuria

AU - Masdeu-Bulto, Anna

PY - 2007

Y1 - 2007

N2 - Dehydrohalogenation of haloaromatics in ionic liquids derived from ethylmethylimidazolium or similar salts has been performed using Pd-C, Pd(OAc)(2) and other catalysts using formate salts as a hydrogen source. In the ionic liquid [emim][BF4], chlorobenzene was dehalogenated by up to 40 , bromobenzene up to 25 and iodobenzene up to 41 in 2 h. Reactions in the absence of the ionic liquid were also performed

AB - Dehydrohalogenation of haloaromatics in ionic liquids derived from ethylmethylimidazolium or similar salts has been performed using Pd-C, Pd(OAc)(2) and other catalysts using formate salts as a hydrogen source. In the ionic liquid [emim][BF4], chlorobenzene was dehalogenated by up to 40 , bromobenzene up to 25 and iodobenzene up to 41 in 2 h. Reactions in the absence of the ionic liquid were also performed

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JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 3

ER -

Heterogeneous dehalogenation of arylhalides in the presence of ionic liquids

Abstract

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