Heterogeneous Catalysis with Metal Organic Framework (MOF) - derived materials

Dalal S. Alqarni; Gregory P. Knowles; Christian Vogt; Alan L. Chaffee

doi:10.2139/ssrn.3365941

Heterogeneous Catalysis with Metal Organic Framework (MOF) - derived materials

Dalal S. Alqarni, Gregory P. Knowles, Christian Vogt, Alan L. Chaffee

School of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference Paper › Research

Abstract

Novel materials prepared by thermal transformation of the metal organic framework (MOF) precursors M-MIL-140C-10 (M= Ru, Rh, Pd and In) were studied for their activity as heterogeneous catalysts for the conversion of CO₂ into organic chemicals and fuels. These MOFs were compositionally and morphologically transformed when heated in a mixture of CO₂ and H₂ (1:3). Transformation of Ru-MIL-140C-10 provided a material with exceptionally high activity for the conversion of CO₂ to methane. TEM results show that the active form of the catalyst was a partially degraded (‘unzipped’) MOF structure where Ru⁰ and ZrO₂ nanoparticles (2-3 nm diameter) were dispersed upon carbonaceous ribbons.

Original language	English
Title of host publication	SSRN
Subtitle of host publication	GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies
Number of pages	5
DOIs	https://doi.org/10.2139/ssrn.3365941
Publication status	Published - 2018
Event	International Conference on Greenhouse Gas Control Technologies 2018 - Melbourne, Australia Duration: 21 Oct 2018 → 25 Oct 2018 Conference number: 14th https://ghgt.info (Website)

Conference

Conference	International Conference on Greenhouse Gas Control Technologies 2018
Abbreviated title	GHGT 2018
Country/Territory	Australia
City	Melbourne
Period	21/10/18 → 25/10/18
Internet address	https://ghgt.info (Website)

Keywords

CO2 conversion
fuels
gas phase heterogeneous catalysis
greenhouse gas
metal-organic frameworks (MOFs)

Access to Document

10.2139/ssrn.3365941Licence: Unspecified

Cite this

@inproceedings{3fd2aae7c81e4cb6b5992811bb30a2c6,

title = "Heterogeneous Catalysis with Metal Organic Framework (MOF) - derived materials",

abstract = "Novel materials prepared by thermal transformation of the metal organic framework (MOF) precursors M-MIL-140C-10 (M= Ru, Rh, Pd and In) were studied for their activity as heterogeneous catalysts for the conversion of CO2 into organic chemicals and fuels. These MOFs were compositionally and morphologically transformed when heated in a mixture of CO2 and H2 (1:3). Transformation of Ru-MIL-140C-10 provided a material with exceptionally high activity for the conversion of CO2 to methane. TEM results show that the active form of the catalyst was a partially degraded ({\textquoteleft}unzipped{\textquoteright}) MOF structure where Ru0 and ZrO2 nanoparticles (2-3 nm diameter) were dispersed upon carbonaceous ribbons.",

keywords = "CO2 conversion, fuels, gas phase heterogeneous catalysis, greenhouse gas, metal-organic frameworks (MOFs)",

author = "Alqarni, {Dalal S.} and Knowles, {Gregory P.} and Christian Vogt and Chaffee, {Alan L.}",

note = "Funding Information: The authors acknowledge use of the facilities, and the assistance of Dr. Tim Williams, at the Monash Centre for Electron Microscopy. Alqarni acknowledges the support of a Saudi Arabian Government csharsohip. l Funding Information: The authors acknowledge use of the facilities, and the assistance of Dr. Tim Williams, at the Monash Centre for Electron Microscopy. Alqarni acknowledges the support of a Saudi Arabian Government scholarship. Publisher Copyright: {\textcopyright} 2018 GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies. All rights reserved.; International Conference on Greenhouse Gas Control Technologies 2018, GHGT 2018 ; Conference date: 21-10-2018 Through 25-10-2018",

year = "2018",

doi = "10.2139/ssrn.3365941",

language = "English",

booktitle = "SSRN",

url = "https://ghgt.info",

}

Alqarni, DS, Knowles, GP, Vogt, C & Chaffee, AL 2018, Heterogeneous Catalysis with Metal Organic Framework (MOF) - derived materials. in SSRN: GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies. International Conference on Greenhouse Gas Control Technologies 2018, Melbourne, Victoria, Australia, 21/10/18. https://doi.org/10.2139/ssrn.3365941

TY - GEN

T1 - Heterogeneous Catalysis with Metal Organic Framework (MOF) - derived materials

AU - Alqarni, Dalal S.

AU - Knowles, Gregory P.

AU - Vogt, Christian

AU - Chaffee, Alan L.

N1 - Conference code: 14th

PY - 2018

Y1 - 2018

N2 - Novel materials prepared by thermal transformation of the metal organic framework (MOF) precursors M-MIL-140C-10 (M= Ru, Rh, Pd and In) were studied for their activity as heterogeneous catalysts for the conversion of CO2 into organic chemicals and fuels. These MOFs were compositionally and morphologically transformed when heated in a mixture of CO2 and H2 (1:3). Transformation of Ru-MIL-140C-10 provided a material with exceptionally high activity for the conversion of CO2 to methane. TEM results show that the active form of the catalyst was a partially degraded (‘unzipped’) MOF structure where Ru0 and ZrO2 nanoparticles (2-3 nm diameter) were dispersed upon carbonaceous ribbons.

AB - Novel materials prepared by thermal transformation of the metal organic framework (MOF) precursors M-MIL-140C-10 (M= Ru, Rh, Pd and In) were studied for their activity as heterogeneous catalysts for the conversion of CO2 into organic chemicals and fuels. These MOFs were compositionally and morphologically transformed when heated in a mixture of CO2 and H2 (1:3). Transformation of Ru-MIL-140C-10 provided a material with exceptionally high activity for the conversion of CO2 to methane. TEM results show that the active form of the catalyst was a partially degraded (‘unzipped’) MOF structure where Ru0 and ZrO2 nanoparticles (2-3 nm diameter) were dispersed upon carbonaceous ribbons.

KW - CO2 conversion

KW - fuels

KW - gas phase heterogeneous catalysis

KW - greenhouse gas

KW - metal-organic frameworks (MOFs)

UR - http://www.scopus.com/inward/record.url?scp=85181583315&partnerID=8YFLogxK

U2 - 10.2139/ssrn.3365941

DO - 10.2139/ssrn.3365941

M3 - Conference Paper

AN - SCOPUS:85181583315

BT - SSRN

T2 - International Conference on Greenhouse Gas Control Technologies 2018

Y2 - 21 October 2018 through 25 October 2018

ER -

Heterogeneous Catalysis with Metal Organic Framework (MOF) - derived materials

Abstract

Conference

Keywords

Access to Document

Other files and links

Centre for Electron Microscopy (MCEM)

Cite this

Heterogeneous Catalysis with Metal Organic Framework (MOF) - derived materials

Abstract

Conference

Keywords

Access to Document

Other files and links

Equipment

Centre for Electron Microscopy (MCEM)

Cite this