Heteroatom nitrogen- and boron-doping as a facile strategy to improve photocatalytic activity of standalone reduced graphene oxide in hydrogen evolution

Lutfi K. Putri, Boon Junn Ng, Wee Jun Ong, Hing Wah Lee, Wei Sea Chang, Siang Piao Chai

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    86 Citations (Scopus)

    Abstract

    Owing to its superior properties and versatility, graphene has been proliferating the energy research scene in the past decade. In this contribution, nitrogen (N-) and boron (B-) doped reduced graphene oxide (rGO) variants were investigated as a sole photocatalyst for the green production of H2 and their properties with respect to photocatalysis were elucidated for the first time. N- and B-rGOs were facilely prepared via the pyrolysis of graphene oxide with urea and boron anhydride as their respective dopant source. The pyrolysis temperature was varied (600-800 °C for N-rGO and 800-1000 °C for B-rGO) in order to modify dopant loading percentage (%) which was found to be influential to photocatalytic activity. N-rGO600 (8.26 N at%) and B-rGO1000 (3.59 B at%), which holds the highest at% from each of their party, exhibited the highest H2 activity. Additionally, the effects of the nature of N and B bonding configuration in H2 photoactivity were also examined. This study demonstrates the importance of dopant atoms in graphene, rendering doping as an effective strategy to bolster photocatalytic activity for standalone graphene derivative photocatalysts.

    Original languageEnglish
    Pages (from-to)4558-4569
    Number of pages12
    JournalACS Applied Materials & Interfaces
    Volume9
    Issue number5
    DOIs
    Publication statusPublished - 8 Feb 2017

    Keywords

    • boron
    • doped
    • graphene
    • hydrogen
    • nitrogen
    • photocatalyst

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