Halogen-exchange reactions and barriers to torsion around N-S bonds in halogeno-sulphinamides

W. R. Jackson, T. G. Kee, W. B. Jennings

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The n.m.r. spectra of a series of halogeno-sulphinamides are described at varying temperatures and concentrations; the spectra are intepreted in terms of restricted torsion around the N-S bond (ΔG 35-60 kJ mol-1) and rapid halogen-exchange reactions in the case of the chloro- and bromo-compounds.

Original languageEnglish
Pages (from-to)1154-1155
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number20
Publication statusPublished - 1 Dec 1972
Externally publishedYes

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