Halogen-exchange reactions and barriers to torsion around N-S bonds in halogeno-sulphinamides

W. R. Jackson; T. G. Kee; W. B. Jennings

doi:10.1039/C39720001154

Halogen-exchange reactions and barriers to torsion around N-S bonds in halogeno-sulphinamides

W. R. Jackson, T. G. Kee, W. B. Jennings

Research output: Contribution to journal › Article › Research › peer-review

11 Citations (Scopus)

Abstract

The n.m.r. spectra of a series of halogeno-sulphinamides are described at varying temperatures and concentrations; the spectra are intepreted in terms of restricted torsion around the N-S bond (ΔG^‡ 35-60 kJ mol^-1) and rapid halogen-exchange reactions in the case of the chloro- and bromo-compounds.

Original language	English
Pages (from-to)	1154-1155
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	0
Issue number	20
DOIs	https://doi.org/10.1039/C39720001154
Publication status	Published - 1 Dec 1972
Externally published	Yes

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title = "Halogen-exchange reactions and barriers to torsion around N-S bonds in halogeno-sulphinamides",

abstract = "The n.m.r. spectra of a series of halogeno-sulphinamides are described at varying temperatures and concentrations; the spectra are intepreted in terms of restricted torsion around the N-S bond (ΔG‡ 35-60 kJ mol-1) and rapid halogen-exchange reactions in the case of the chloro- and bromo-compounds.",

author = "Jackson, {W. R.} and Kee, {T. G.} and Jennings, {W. B.}",

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AU - Kee, T. G.

AU - Jennings, W. B.

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AB - The n.m.r. spectra of a series of halogeno-sulphinamides are described at varying temperatures and concentrations; the spectra are intepreted in terms of restricted torsion around the N-S bond (ΔG‡ 35-60 kJ mol-1) and rapid halogen-exchange reactions in the case of the chloro- and bromo-compounds.

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Halogen-exchange reactions and barriers to torsion around N-S bonds in halogeno-sulphinamides

Abstract

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