Half sandwich complexes derived from a 2,4-diphosphastibolyl ring anion

Steven J. Black; Cameron Jones

doi:10.1016/S0022-328X(96)06884-2

Half sandwich complexes derived from a 2,4-diphosphastibolyl ring anion

Steven J. Black
, Cameron Jones

Research output: Contribution to journal › Article › Research › peer-review

10 Citations (Scopus)

Abstract

The reaction of the hetero-ring anion [C₂Bu^t₂P₂Sb]^- with [{M(η⁴-1,5-C₈H₁₂)Cl}₂], M = Rh, Ir, leads to the formation of [M(η⁵-C₂Bu^t₂P₂Sb)(η₄-1,5-C₈H₁₂)], M = Rh 7, Ir 8. Treatment of CoCl₂ with either an equimolar mixture of [C₂Bu^t₂P₂Sb]^- and [C₅Me₅]^-, or two equivalents of [C₂Bu^t₂P₂Sb]^- affords the compounds [Co(η⁵-C₅Me₅)(η⁴-C₂Bu^t₂HP₂Sb)], 11, and [Co(η⁵-C₂Bu^t₂P₂Sb)(η⁴-C₂Bu^t₂HP₂Sb)], 12, which represent the first examples of diphosphastibacyclopentadiene complexes; the X-ray crystal structures of 7 and 11 are reported.

Original language	English
Pages (from-to)	89-94
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	534
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(96)06884-2
Publication status	Published - 28 Apr 1997
Externally published	Yes

Keywords

Antimony
Diphosphastibacyclopentadiene
Diphosphastibolyl
Low coordination
Phosphorus

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10.1016/S0022-328X(96)06884-2

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@article{1ec7e61924044364a626a5b50cd4eb33,

title = "Half sandwich complexes derived from a 2,4-diphosphastibolyl ring anion",

abstract = "The reaction of the hetero-ring anion [C2But2P2Sb]- with [\{M(η4-1,5-C8H12)Cl\}2], M = Rh, Ir, leads to the formation of [M(η5-C2But2P2Sb)(η4-1,5-C8H12)], M = Rh 7, Ir 8. Treatment of CoCl2 with either an equimolar mixture of [C2But2P2Sb]- and [C5Me5]-, or two equivalents of [C2But2P2Sb]- affords the compounds [Co(η5-C5Me5)(η4-C2But2HP2Sb)], 11, and [Co(η5-C2But2P2Sb)(η4-C2But2HP2Sb)], 12, which represent the first examples of diphosphastibacyclopentadiene complexes; the X-ray crystal structures of 7 and 11 are reported.",

keywords = "Antimony, Diphosphastibacyclopentadiene, Diphosphastibolyl, Low coordination, Phosphorus",

author = "Black, \{Steven J.\} and Cameron Jones",

year = "1997",

month = apr,

day = "28",

doi = "10.1016/S0022-328X(96)06884-2",

language = "English",

volume = "534",

pages = "89--94",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier BV",

number = "1-2",

}

TY - JOUR

T1 - Half sandwich complexes derived from a 2,4-diphosphastibolyl ring anion

AU - Black, Steven J.

AU - Jones, Cameron

PY - 1997/4/28

Y1 - 1997/4/28

N2 - The reaction of the hetero-ring anion [C2But2P2Sb]- with [{M(η4-1,5-C8H12)Cl}2], M = Rh, Ir, leads to the formation of [M(η5-C2But2P2Sb)(η4-1,5-C8H12)], M = Rh 7, Ir 8. Treatment of CoCl2 with either an equimolar mixture of [C2But2P2Sb]- and [C5Me5]-, or two equivalents of [C2But2P2Sb]- affords the compounds [Co(η5-C5Me5)(η4-C2But2HP2Sb)], 11, and [Co(η5-C2But2P2Sb)(η4-C2But2HP2Sb)], 12, which represent the first examples of diphosphastibacyclopentadiene complexes; the X-ray crystal structures of 7 and 11 are reported.

AB - The reaction of the hetero-ring anion [C2But2P2Sb]- with [{M(η4-1,5-C8H12)Cl}2], M = Rh, Ir, leads to the formation of [M(η5-C2But2P2Sb)(η4-1,5-C8H12)], M = Rh 7, Ir 8. Treatment of CoCl2 with either an equimolar mixture of [C2But2P2Sb]- and [C5Me5]-, or two equivalents of [C2But2P2Sb]- affords the compounds [Co(η5-C5Me5)(η4-C2But2HP2Sb)], 11, and [Co(η5-C2But2P2Sb)(η4-C2But2HP2Sb)], 12, which represent the first examples of diphosphastibacyclopentadiene complexes; the X-ray crystal structures of 7 and 11 are reported.

KW - Antimony

KW - Diphosphastibacyclopentadiene

KW - Diphosphastibolyl

KW - Low coordination

KW - Phosphorus

UR - https://www.scopus.com/pages/publications/0031589130

U2 - 10.1016/S0022-328X(96)06884-2

DO - 10.1016/S0022-328X(96)06884-2

M3 - Article

AN - SCOPUS:0031589130

SN - 0022-328X

VL - 534

SP - 89

EP - 94

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Half sandwich complexes derived from a 2,4-diphosphastibolyl ring anion

Abstract

Keywords

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