Green synthesis of soluble polyphenol: Oxidative polymerization of phenol in water

Kei Saito, Gangyong Sun, Hiroyuki Nishide

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    14 Citations (Scopus)

    Abstract

    The simple stirring of phenol with an oxidant in water provided a novel green way to synthesize soluble polyphenol. The soluble polyphenol obtained had a high poly(phenylene oxide) unit ratio, poly(phenyleneoxide)/poly(phenylene)=ca. 80/20. Additionally, the insoluble fraction was identified as a poly(phenyleneoxide), which has a crosslinking point for every 5.5×103 molecular weight. These results suggest that oxidative polymerization in water can be run in a manner to control the coupling selectivity of phenol. Both the soluble polyphenol and the insoluble fraction showed a high thermal stability. Oxidative polymerization in water provides the potential for a formaldehyde-free and regioselected soluble poly(phenyleneoxide) from phenol.

    Original languageEnglish
    Pages (from-to)47-51
    Number of pages5
    JournalGreen Chemistry Letters and Reviews
    Volume1
    Issue number1
    DOIs
    Publication statusPublished - 1 Jan 2007

    Keywords

    • Oxidative polymerization
    • Phenol
    • Phenolic resin
    • Polyphenyleneoxide
    • Water solvent

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