Gold nanoparticles in novel green deep eutectic solvents: self-limited growth, self-assembly & catalytic implications

Maeve O'Neill, Vikram Singh Raghuwanshi, Robert Wendt, Markus Wollgarten, Armin Hoell, Klaus Rademann

Research output: Contribution to journalArticleResearchpeer-review

7 Citations (Scopus)

Abstract

In this article, we are reporting the catalytic activity of gold nanoparticles (AuNPs) dispersed in a novel eco-friendly Deep Eutectic Solvent (DES; choline chloride and urea) at room temperature. A low energy sputter deposition method is employed to synthesize AuNPs on the DES surface. This is a simple, economical and clean method for producing monodisperse gold nanoparticles by a self-limited growth mechanism. Detailed Small Angle X-ray Scattering (SAXS), UV-Vis and Transmission Electron Microscopy (TEM) investigations show the formation of spherical AuNPs of 5 nm in diameter. Moreover, these particles have a strong tendency to self-assemble at the DES surface as well as into the bulk. This is a new addition to a novel generation of gold based catalysts. The catalytic activity of Au nanoparticles in DES is revealed quantitatively by analyzing the apparent conversion reaction rate constant Kapp of para-nitrophenol to paraaminophenol in the presence of sodium borohydride. Catalytic activity reported in the present article ismuch faster (kapp = 0.34 s-1) than the rate reported earlier (kapp = 0.030 min-1) by Chirea et al. for gold nanowire networks [Langmuir, 2011, 27, 3906]. In agreement with the literature, we explain the higher catalytic activity in terms of a larger surface area of AuNPs in a non-self-assembled state.

Original languageEnglish
Pages (from-to)221-234
Number of pages14
JournalZeitschrift fur Physikalische Chemie
Volume229
Issue number1-2
DOIs
Publication statusPublished - 28 Feb 2015
Externally publishedYes

Keywords

  • Catalysis
  • Gold
  • Nanoparticles
  • Para-Nitrophenol Reduction
  • Reaction Kinetics
  • Self-Assembly
  • Self-Limited Growth

Cite this