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GIXRF-NEXAFS investigations on buried ZnO/Si interfaces: A first insight in changes of chemical states due to annealing of the specimen

  • M. Pagels
  • , F. Reinhardt
  • , B. Pollakowski
  • , M. Roczen
  • , C. Becker
  • , K. Lips
  • , B. Rech
  • , B. Kanngießer
  • , B. Beckhoff

Research output: Contribution to journalArticleResearchpeer-review

Abstract

GIXRF-NEXAFS is a combination of X-ray spectroscopy methods which allows for a non-destructive, depth-dependant chemical speciation of layer systems in the range of a few to several hundred nanometers. We applied this technique to a model system for thin-film silicon solar cells, a Si/ZnO layer system, which was investigated in its as-deposited and its annealed state. By means of total reflection at the buried ZnO/Si interface we could gain access to chemical information on the interface. In addition, a diffusion of contaminants from the ZnO into the Si was observed after annealing.

Original languageEnglish
Pages (from-to)370-373
Number of pages4
JournalNuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
Volume268
Issue number3-4
DOIs
Publication statusPublished - Feb 2010
Externally publishedYes

Keywords

  • Depth profiles
  • Grazing incidence X-ray fluorescence
  • Near edge X-ray absorption fine structure spectroscopy
  • Reference-free
  • Silicon thin-film solar cell
  • ZnO/Si interface

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