Geometrical preferences of complexes of terpyridine N-oxide ligands: Synthesis and crystal structures of nickel(II) with terpyridine 1,1′1″ -trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide

Angelo J. Amoroso, Miles W. Burrows, Anthony A. Dickinson, Cameron Jones, David J. Willock, Wing Tak Wong

Research output: Contribution to journalArticleResearchpeer-review

11 Citations (Scopus)

Abstract

[NiL2][ClO4]2 complexes (L = terpyridine 1,1′1″-trioxide, terpyridine 1,1″ -dioxide and terpyridine 1-oxide) have been prepared and crystallographically characterised; data shows a predictable variation in ligand conformation, such as facial or meridonal binding, which is in agreement with DFT calculations.

Original languageEnglish
Pages (from-to)225-227
Number of pages3
JournalJournal of the Chemical Society, Dalton Transactions
Issue number3
DOIs
Publication statusPublished - 1 Dec 2001

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