Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection: Remarkably nucleophile-resistant (dimethylamino)borylene complexes

David A. Addy; Glesni A. Pierce; Dragoslav Vidovic; Dibyendu Mallick; Eluvathingal D. Jemmis; Jose M. Goicoechea; Simon Aldridge

doi:10.1021/ja101192e

Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection: Remarkably nucleophile-resistant (dimethylamino)borylene complexes

David A. Addy, Glesni A. Pierce, Dragoslav Vidovic, Dibyendu Mallick, Eluvathingal D. Jemmis, Jose M. Goicoechea, Simon Aldridge

Research output: Contribution to journal › Article › Research › peer-review

21 Citations (Scopus)

Abstract

Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents.

Original language	English
Pages (from-to)	4586-4588
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	132
Issue number	13
DOIs	https://doi.org/10.1021/ja101192e
Publication status	Published - 7 Apr 2010
Externally published	Yes

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10.1021/ja101192e

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title = "Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection: Remarkably nucleophile-resistant (dimethylamino)borylene complexes",

abstract = "Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents.",

author = "Addy, {David A.} and Pierce, {Glesni A.} and Dragoslav Vidovic and Dibyendu Mallick and Jemmis, {Eluvathingal D.} and Goicoechea, {Jose M.} and Simon Aldridge",

year = "2010",

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language = "English",

volume = "132",

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Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection: Remarkably nucleophile-resistant (dimethylamino)borylene complexes. / Addy, David A.; Pierce, Glesni A.; Vidovic, Dragoslav et al.
In: Journal of the American Chemical Society, Vol. 132, No. 13, 07.04.2010, p. 4586-4588.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection

T2 - Remarkably nucleophile-resistant (dimethylamino)borylene complexes

AU - Addy, David A.

AU - Pierce, Glesni A.

AU - Vidovic, Dragoslav

AU - Mallick, Dibyendu

AU - Jemmis, Eluvathingal D.

AU - Goicoechea, Jose M.

AU - Aldridge, Simon

PY - 2010/4/7

Y1 - 2010/4/7

N2 - Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents.

AB - Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents.

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U2 - 10.1021/ja101192e

DO - 10.1021/ja101192e

M3 - Article

AN - SCOPUS:77950801123

SN - 0002-7863

VL - 132

SP - 4586

EP - 4588

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 13

ER -

Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection: Remarkably nucleophile-resistant (dimethylamino)borylene complexes

Abstract

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