Ge_10O_28单元构建的两个三维锗酸盐结构: H_3O)_4Ge_7O_16·3H_2O和K_4Ge_9O_20

Ya Ming Zhou; Zhi Chen Liu; Zhen Xia Chen; Lin Hong Weng; Dong Yuan Zhao

Ge_10O_28单元构建的两个三维锗酸盐结构: H_3O)_4Ge_7O_16·3H_2O和K_4Ge_9O_20

Translated title of the contribution: (H3O)4Ge7O16·3H 2O and K4Ge9O20: Two microporous germanates constructed by Ge10O28 units

Ya Ming Zhou, Zhi Chen Liu, Zhen Xia Chen, Lin Hong Weng, Dong Yuan Zhao

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

Quasi-solvothermal syntheses and X-ray crystal structures of two germanates (H₃O)₄Ge₇O₁₆ · 3H ₂O and K₄Ge₉O₂₀ are presented. Although both structures are built up from the same rock-like secondary building units (SBUs) Ge₁₀O₂₈, the frameworks are different because of the different connect manners of SBUs. Crystal data for H ₄Ge₇O₁₆·7H₂O: M_r = 894.27, space group P-43m, a = 0.77309(18) nm, V = 0.46205(19) nm³, Z = 1, Mo Kα, λ = 0.071073 nm, R(F) = 3.48%, wR(F²) = 8.39% for 20 parameters and 228 reflections with I > 2σ(I). Crystal data for K₄Ge₉O₂₀: M_r = 1129.71, space group I4(1)/a, a = 1.5002(3) nm, c = 0.7383(2) nm, V = 1.6618(7) nm ³, Z = 4, Mo Kα, R(F) = 3.92%, wR(F²) = 11.97% for 75 parameters and 922 reflections with I > 2σ(I).

Translated title of the contribution	(H3O)4Ge7O16·3H 2O and K4Ge9O20: Two microporous germanates constructed by Ge10O28 units
Original language	Chinese
Pages (from-to)	382-387
Number of pages	6
Journal	Acta Chimica Sinica
Volume	61
Issue number	3
Publication status	Published - 1 Dec 2003
Externally published	Yes

Keywords

Germanate
Microporous material
Secondary building unit
Solvothermal synthesis
Structure

Cite this

@article{f1d00383018e4d829a798dac6a540213,

title = "Ge_10O_28单元构建的两个三维锗酸盐结构: H_3O)_4Ge_7O_16·3H_2O和K_4Ge_9O_20",

abstract = "Quasi-solvothermal syntheses and X-ray crystal structures of two germanates (H3O)4Ge7O16 · 3H 2O and K4Ge9O20 are presented. Although both structures are built up from the same rock-like secondary building units (SBUs) Ge10O28, the frameworks are different because of the different connect manners of SBUs. Crystal data for H 4Ge7O16·7H2O: Mr = 894.27, space group P-43m, a = 0.77309(18) nm, V = 0.46205(19) nm3, Z = 1, Mo Kα, λ = 0.071073 nm, R(F) = 3.48%, wR(F2) = 8.39% for 20 parameters and 228 reflections with I > 2σ(I). Crystal data for K4Ge9O20: Mr = 1129.71, space group I4(1)/a, a = 1.5002(3) nm, c = 0.7383(2) nm, V = 1.6618(7) nm 3, Z = 4, Mo Kα, R(F) = 3.92%, wR(F2) = 11.97% for 75 parameters and 922 reflections with I > 2σ(I).",

keywords = "Germanate, Microporous material, Secondary building unit, Solvothermal synthesis, Structure",

author = "Zhou, {Ya Ming} and Liu, {Zhi Chen} and Chen, {Zhen Xia} and Weng, {Lin Hong} and Zhao, {Dong Yuan}",

year = "2003",

month = dec,

day = "1",

language = "Chinese",

volume = "61",

pages = "382--387",

journal = "Acta Chimica Sinica",

issn = "0567-7351",

publisher = "Shanghai Institute of Organic Chemistry",

number = "3",

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TY - JOUR

T1 - Ge_10O_28单元构建的两个三维锗酸盐结构

T2 - H_3O)_4Ge_7O_16·3H_2O和K_4Ge_9O_20

AU - Zhou, Ya Ming

AU - Liu, Zhi Chen

AU - Chen, Zhen Xia

AU - Weng, Lin Hong

AU - Zhao, Dong Yuan

PY - 2003/12/1

Y1 - 2003/12/1

N2 - Quasi-solvothermal syntheses and X-ray crystal structures of two germanates (H3O)4Ge7O16 · 3H 2O and K4Ge9O20 are presented. Although both structures are built up from the same rock-like secondary building units (SBUs) Ge10O28, the frameworks are different because of the different connect manners of SBUs. Crystal data for H 4Ge7O16·7H2O: Mr = 894.27, space group P-43m, a = 0.77309(18) nm, V = 0.46205(19) nm3, Z = 1, Mo Kα, λ = 0.071073 nm, R(F) = 3.48%, wR(F2) = 8.39% for 20 parameters and 228 reflections with I > 2σ(I). Crystal data for K4Ge9O20: Mr = 1129.71, space group I4(1)/a, a = 1.5002(3) nm, c = 0.7383(2) nm, V = 1.6618(7) nm 3, Z = 4, Mo Kα, R(F) = 3.92%, wR(F2) = 11.97% for 75 parameters and 922 reflections with I > 2σ(I).

AB - Quasi-solvothermal syntheses and X-ray crystal structures of two germanates (H3O)4Ge7O16 · 3H 2O and K4Ge9O20 are presented. Although both structures are built up from the same rock-like secondary building units (SBUs) Ge10O28, the frameworks are different because of the different connect manners of SBUs. Crystal data for H 4Ge7O16·7H2O: Mr = 894.27, space group P-43m, a = 0.77309(18) nm, V = 0.46205(19) nm3, Z = 1, Mo Kα, λ = 0.071073 nm, R(F) = 3.48%, wR(F2) = 8.39% for 20 parameters and 228 reflections with I > 2σ(I). Crystal data for K4Ge9O20: Mr = 1129.71, space group I4(1)/a, a = 1.5002(3) nm, c = 0.7383(2) nm, V = 1.6618(7) nm 3, Z = 4, Mo Kα, R(F) = 3.92%, wR(F2) = 11.97% for 75 parameters and 922 reflections with I > 2σ(I).

KW - Germanate

KW - Microporous material

KW - Secondary building unit

KW - Solvothermal synthesis

KW - Structure

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M3 - Article

AN - SCOPUS:33750505731

SN - 0567-7351

VL - 61

SP - 382

EP - 387

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

IS - 3

ER -

Ge_10O_28单元构建的两个三维锗酸盐结构: H_3O)_4Ge_7O_16·3H_2O和K_4Ge_9O_20

Abstract

Keywords

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