Fluid-mediated parallel self-assembly of polymeric micro-capsules for liquid encapsulation and release

Loïc Jacot-Descombes, Cristina Martin-Olmos, Maurizio Rosario Gullo, Victor Javier Cadarso, Gregory Mermoud, Luis Guillermo Villanueva, Massimo Mastrangeli, Alcherio Martinoli, Jürgen Brugger

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8 Citations (Scopus)

Abstract

Fluid-mediated self-assembly is one of the most promising routes for assembling and packaging smart microsystems in a scalable and cost-efficient way. In this work the pairwise fluidic self-assembly of 100 μm-sized SU-8 cylinders is studied with respect to two driving mechanisms: capillary forces at the liquid-air interface and the hydrophobic effect while fully immersed in liquid. The pairwise self-assembly is controlled by shape recognition and selective surface functionalization. Surface energy contrast is introduced through oxygen plasma treatment and local deposition of a hydrophobic self-assembled monolayer, respectively leading to face-selective hydrophilic and hydrophobic behavior. When in bulk liquid, after less than a day face-wise self-assembly of more than 650 components is achieved with a yield of up to 97% and with less than 1% of the cylinders assembled incorrectly. This technique is subsequently adopted for self-assembling half-capsules into closed micro-capsules, thereby entrapping a liquid during their self-assembly. The release of the liquid can subsequently be triggered in another medium, as intended for applications involving e.g. chemical reactors, environmental engineering and drug release.

Original languageEnglish
Pages (from-to)9931-9938
Number of pages8
JournalSoft Matter
Volume9
Issue number41
DOIs
Publication statusPublished - 7 Nov 2013
Externally publishedYes

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