First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η1-complexes [M(CO)5(P2SeC2But2)] (M=Cr, W) and [W(CO)5(P2TeC2But2)]

M. D. Francis; D. E. Hibbs; P. B. Hitchcock; M. B. Hursthouse; C. Jones; T. MacKewitz; J. F. Nixon; L. Nyulaszi; M. Regitz; N. Sakarya

doi:10.1016/S0022-328X(98)01141-3

First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η¹-complexes [M(CO)₅(P₂SeC₂Bu^t₂)] (M=Cr, W) and [W(CO)₅(P₂TeC₂Bu^t₂)]

M. D. Francis, D. E. Hibbs, P. B. Hitchcock, M. B. Hursthouse, C. Jones, T. MacKewitz, J. F. Nixon, L. Nyulaszi, M. Regitz, N. Sakarya

Research output: Contribution to journal › Article › Research › peer-review

28 Citations (Scopus)

Abstract

The molecular geometries of the 1,2,4-selenadiphosphole and the 1,2,4-telluradiphosphole aromatic ring systems, established by single crystal X-ray diffraction studies on their metal pentacarbonyl complexes, are presented and discussed together with theoretical data.

Original language	English
Pages (from-to)	156-160
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	580
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(98)01141-3
Publication status	Published - 15 May 1999
Externally published	Yes

Keywords

Carbonyls
Chromium
Complexes
Selenadiphosphole
Telluradiphosphole
Tungsten

Access to Document

10.1016/S0022-328X(98)01141-3

Cite this

Francis, M. D., Hibbs, D. E., Hitchcock, P. B., Hursthouse, M. B., Jones, C., MacKewitz, T., Nixon, J. F., Nyulaszi, L., Regitz, M., & Sakarya, N. (1999). First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η¹-complexes [M(CO)₅(P₂SeC₂Bu^t₂)] (M=Cr, W) and [W(CO)₅(P₂TeC₂Bu^t₂)]. Journal of Organometallic Chemistry, 580(1), 156-160. https://doi.org/10.1016/S0022-328X(98)01141-3

Francis, M. D. ; Hibbs, D. E. ; Hitchcock, P. B. ; Hursthouse, M. B. ; Jones, C. ; MacKewitz, T. ; Nixon, J. F. ; Nyulaszi, L. ; Regitz, M. ; Sakarya, N. / First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η¹-complexes [M(CO)₅(P₂SeC₂Bu^t₂)] (M=Cr, W) and [W(CO)₅(P₂TeC₂Bu^t₂)]. In: Journal of Organometallic Chemistry. 1999 ; Vol. 580, No. 1. pp. 156-160.

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title = "First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η1-complexes [M(CO)5(P2SeC2But2)] (M=Cr, W) and [W(CO)5(P2TeC2But2)]",

abstract = "The molecular geometries of the 1,2,4-selenadiphosphole and the 1,2,4-telluradiphosphole aromatic ring systems, established by single crystal X-ray diffraction studies on their metal pentacarbonyl complexes, are presented and discussed together with theoretical data.",

keywords = "Carbonyls, Chromium, Complexes, Selenadiphosphole, Telluradiphosphole, Tungsten",

author = "Francis, {M. D.} and Hibbs, {D. E.} and Hitchcock, {P. B.} and Hursthouse, {M. B.} and C. Jones and T. MacKewitz and Nixon, {J. F.} and L. Nyulaszi and M. Regitz and N. Sakarya",

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Francis, MD, Hibbs, DE, Hitchcock, PB, Hursthouse, MB, Jones, C, MacKewitz, T, Nixon, JF, Nyulaszi, L, Regitz, M & Sakarya, N 1999, 'First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η¹-complexes [M(CO)₅(P₂SeC₂Bu^t₂)] (M=Cr, W) and [W(CO)₅(P₂TeC₂Bu^t₂)]', Journal of Organometallic Chemistry, vol. 580, no. 1, pp. 156-160. https://doi.org/10.1016/S0022-328X(98)01141-3

First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η¹-complexes [M(CO)₅(P₂SeC₂Bu^t₂)] (M=Cr, W) and [W(CO)₅(P₂TeC₂Bu^t₂)]. / Francis, M. D.; Hibbs, D. E.; Hitchcock, P. B.; Hursthouse, M. B.; Jones, C.; MacKewitz, T.; Nixon, J. F.; Nyulaszi, L.; Regitz, M.; Sakarya, N.

In: Journal of Organometallic Chemistry, Vol. 580, No. 1, 15.05.1999, p. 156-160.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η1-complexes [M(CO)5(P2SeC2But2)] (M=Cr, W) and [W(CO)5(P2TeC2But2)]

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AU - Hursthouse, M. B.

AU - Jones, C.

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AU - Sakarya, N.

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KW - Chromium

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