First CuII diamondoid net with 2-fold interpenetrating frameworks. The role of anions in the construction of the supramolecular arrays

Miao Du; Xian-He Bu; Ya-Mei Guo; He Liu; Stuart R Batten; Joan Ribas; Thomas C W Mak

doi:10.1021/ic025559

First Cu^II diamondoid net with 2-fold interpenetrating frameworks. The role of anions in the construction of the supramolecular arrays

Miao Du, Xian-He Bu, Ya-Mei Guo, He Liu, Stuart R Batten, Joan Ribas, Thomas C W Mak

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

166 Citations (Scopus)

Abstract

The synthesis and crystal structure of the three-dimensional coordination polymer of an angular dipyridyl ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L) and Cu(ClO4)2, exhibiting the first CuII diamondoid network with 2-fold interpenetration, {[Cu(L)2(H2O)2](ClO4) (OH)(H2O)2.5}n (1), together with the Cu(OAc)2 complex of L, [Cu(L)2(OAc)2- (H2O)](H2O)2(CH3OH) (2), with an unexpected mononuclear structure, are reported. Crystal data for 1: tetragonal, space group I41/a, a = b = 13.477(3) Å, c = 46.167(13) Å, Z = 8. Crystal data for 2: triclinic, space group P1, a = 7.847(2) Å, b = 13.189(4) A, c = 15.948(5) Å, α = 75.225(7)° β = 79.945(6)°, γ = 77.540(5)°, Z = 2. The magnetic properties and anion effect are also discussed.

Original language	English
Pages (from-to)	4904-4908
Number of pages	5
Journal	Inorganic Chemistry
Volume	41
Issue number	19
DOIs	https://doi.org/10.1021/ic025559
Publication status	Published - 2002

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@article{dcfd8e0d1b8b4f558b3b804a828cd553,

title = "First CuII diamondoid net with 2-fold interpenetrating frameworks. The role of anions in the construction of the supramolecular arrays",

abstract = "The synthesis and crystal structure of the three-dimensional coordination polymer of an angular dipyridyl ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L) and Cu(ClO4)2, exhibiting the first CuII diamondoid network with 2-fold interpenetration, {[Cu(L)2(H2O)2](ClO4) (OH)(H2O)2.5}n (1), together with the Cu(OAc)2 complex of L, [Cu(L)2(OAc)2- (H2O)](H2O)2(CH3OH) (2), with an unexpected mononuclear structure, are reported. Crystal data for 1: tetragonal, space group I41/a, a = b = 13.477(3) {\AA}, c = 46.167(13) {\AA}, Z = 8. Crystal data for 2: triclinic, space group P1, a = 7.847(2) {\AA}, b = 13.189(4) A, c = 15.948(5) {\AA}, α = 75.225(7)° β = 79.945(6)°, γ = 77.540(5)°, Z = 2. The magnetic properties and anion effect are also discussed.",

author = "Miao Du and Xian-He Bu and Ya-Mei Guo and He Liu and Batten, {Stuart R} and Joan Ribas and Mak, {Thomas C W}",

year = "2002",

doi = "10.1021/ic025559",

language = "English",

volume = "41",

pages = "4904--4908",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - First CuII diamondoid net with 2-fold interpenetrating frameworks. The role of anions in the construction of the supramolecular arrays

AU - Du, Miao

AU - Bu, Xian-He

AU - Guo, Ya-Mei

AU - Liu, He

AU - Batten, Stuart R

AU - Ribas, Joan

AU - Mak, Thomas C W

PY - 2002

Y1 - 2002

N2 - The synthesis and crystal structure of the three-dimensional coordination polymer of an angular dipyridyl ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L) and Cu(ClO4)2, exhibiting the first CuII diamondoid network with 2-fold interpenetration, {[Cu(L)2(H2O)2](ClO4) (OH)(H2O)2.5}n (1), together with the Cu(OAc)2 complex of L, [Cu(L)2(OAc)2- (H2O)](H2O)2(CH3OH) (2), with an unexpected mononuclear structure, are reported. Crystal data for 1: tetragonal, space group I41/a, a = b = 13.477(3) Å, c = 46.167(13) Å, Z = 8. Crystal data for 2: triclinic, space group P1, a = 7.847(2) Å, b = 13.189(4) A, c = 15.948(5) Å, α = 75.225(7)° β = 79.945(6)°, γ = 77.540(5)°, Z = 2. The magnetic properties and anion effect are also discussed.

AB - The synthesis and crystal structure of the three-dimensional coordination polymer of an angular dipyridyl ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L) and Cu(ClO4)2, exhibiting the first CuII diamondoid network with 2-fold interpenetration, {[Cu(L)2(H2O)2](ClO4) (OH)(H2O)2.5}n (1), together with the Cu(OAc)2 complex of L, [Cu(L)2(OAc)2- (H2O)](H2O)2(CH3OH) (2), with an unexpected mononuclear structure, are reported. Crystal data for 1: tetragonal, space group I41/a, a = b = 13.477(3) Å, c = 46.167(13) Å, Z = 8. Crystal data for 2: triclinic, space group P1, a = 7.847(2) Å, b = 13.189(4) A, c = 15.948(5) Å, α = 75.225(7)° β = 79.945(6)°, γ = 77.540(5)°, Z = 2. The magnetic properties and anion effect are also discussed.

U2 - 10.1021/ic025559

DO - 10.1021/ic025559

M3 - Article

SN - 0020-1669

VL - 41

SP - 4904

EP - 4908

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -