Ferroelectric metal-organic framework with a high dielectric constant

Qiong Ye; Yu Mei Song; Guo Xi Wang; Kai Chen; Da Wei Fu; Philip Wai Hong Chan; Jin Song Zhu; Songping D. Huang; Ren Gen Xiong

doi:10.1021/ja060856p

Ferroelectric metal-organic framework with a high dielectric constant

Qiong Ye, Yu Mei Song, Guo Xi Wang, Kai Chen, Da Wei Fu, Philip Wai Hong Chan, Jin Song Zhu, Songping D. Huang, Ren Gen Xiong

Research output: Contribution to journal › Article › Research › peer-review

442 Citations (Scopus)

Abstract

Hydrothermal reaction of (l)-N-(4′-cyanobenzy)-(S)-proline with CdCl₂ as a Lewis acid catalyst and NaN₃ gives colorless block compound 1, in which 1 displays a complicated 3D framework. Ferroelectric and dielectric property measurements reveal that 1 exhibits physical properties comparable to that of a typical ferroelectric compound with a dipole relaxation process and a dielectric constant of ca. 38.6 that makes it, by definition, a high dielectric material.

Original language	English
Pages (from-to)	6554-6555
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	20
DOIs	https://doi.org/10.1021/ja060856p
Publication status	Published - 24 May 2006
Externally published	Yes

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10.1021/ja060856p

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author = "Qiong Ye and Song, {Yu Mei} and Wang, {Guo Xi} and Kai Chen and Fu, {Da Wei} and Chan, {Philip Wai Hong} and Zhu, {Jin Song} and Huang, {Songping D.} and Xiong, {Ren Gen}",

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AU - Song, Yu Mei

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AU - Chen, Kai

AU - Fu, Da Wei

AU - Chan, Philip Wai Hong

AU - Zhu, Jin Song

AU - Huang, Songping D.

AU - Xiong, Ren Gen

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AB - Hydrothermal reaction of (l)-N-(4′-cyanobenzy)-(S)-proline with CdCl2 as a Lewis acid catalyst and NaN3 gives colorless block compound 1, in which 1 displays a complicated 3D framework. Ferroelectric and dielectric property measurements reveal that 1 exhibits physical properties comparable to that of a typical ferroelectric compound with a dipole relaxation process and a dielectric constant of ca. 38.6 that makes it, by definition, a high dielectric material.

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Ferroelectric metal-organic framework with a high dielectric constant

Abstract

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