Far-infrared inversion transition of vinylamine

D. McNaughton; E. G. Robertson

doi:10.1006/jmsp.1994.1009

Far-infrared inversion transition of vinylamine

D. McNaughton, E. G. Robertson

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

The far-infrared spectrum of vinylamine has been recorded and over 1300 transitions between the Coriolis coupled 0⁺ and 0 inversion states of vinylamine have been assigned in the region 20-120 cm^-1. These have been combined with microwave and millimeter-wave data and fitted to give improved values for the rotational and distortion constants. Coriolis coupling constant (μ^y) and inversion splitting (ΔE). Five hundred forty-nine b-dipole moment rotational transitions of (E)-ethanimine have also been assigned in the same spectral region.

Original language	English
Pages (from-to)	80-85
Number of pages	6
Journal	Journal of Molecular Spectroscopy
Volume	163
Issue number	1
DOIs	https://doi.org/10.1006/jmsp.1994.1009
Publication status	Published - Jan 1994

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abstract = "The far-infrared spectrum of vinylamine has been recorded and over 1300 transitions between the Coriolis coupled 0+ and 0 inversion states of vinylamine have been assigned in the region 20-120 cm-1. These have been combined with microwave and millimeter-wave data and fitted to give improved values for the rotational and distortion constants. Coriolis coupling constant (μy) and inversion splitting (ΔE). Five hundred forty-nine b-dipole moment rotational transitions of (E)-ethanimine have also been assigned in the same spectral region.",

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AB - The far-infrared spectrum of vinylamine has been recorded and over 1300 transitions between the Coriolis coupled 0+ and 0 inversion states of vinylamine have been assigned in the region 20-120 cm-1. These have been combined with microwave and millimeter-wave data and fitted to give improved values for the rotational and distortion constants. Coriolis coupling constant (μy) and inversion splitting (ΔE). Five hundred forty-nine b-dipole moment rotational transitions of (E)-ethanimine have also been assigned in the same spectral region.

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Far-infrared inversion transition of vinylamine

Abstract

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