Facile synthesis of CaFe2O4 for visible light driven treatment of polluting palm oil mill effluent: Photokinetic and scavenging study

Ashwin Charles, Maksudur R. Khan, Kim Hoong Ng, Ta Yeong Wu, Jun Wei Lim, Suwimol Wongsakulphasatch, Thongthai Witoon, Chin Kui Cheng

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33 Citations (Scopus)

Abstract

In this paper, a facile synthesis method for CaFe2O4 is introduced that produces a catalyst capable of significant photocatalytic degradation of POME under visible light irradiation. The co-precipitation method was used to produce two catalysts at calcination temperatures of 550 °C and 700 °C dubbed CP550 and CP700. CP550 demonstrated the maximum COD removal of 69.0% at 0.75 g/L catalyst loading after 8 h of visible light irradiation which dropped to 61.0% after three consecutive cycles. SEM images indicated that the higher calcination temperature of CP700 led to annealing which reduced the pore volume (0.025 cm 3 /g) and pore diameter (10.3 nm) while simultaneously creating a smoother and more spherical surface with lower S BET (9.73 m 2 /g). In comparison, CP550 had a rough hair-like surface with higher S BET (27.28 m 2 /g) and pore volume (0.077 cm 3 /g) as evidenced by BET analysis. XRD data indicated the presence of CaFe 5 O 7 in the CP550 composition which was not present in CP700. The presence of Wustite-like FeO structures in CaFe 5 O 7 are likely the cause for lower photoluminescence intensity profile and hence better charge separation of CP550 as these structures in CaFe 2 O 4 have been known to increase resistivity and electron localization. The COD removal of CP550 dropped from 69.0% to just 7.0% upon adding a small quantity of isopropanol into the reaction mixture indicating hydroxyl radicals as the primary reactive oxidative species.

Original languageEnglish
Pages (from-to)522-530
Number of pages9
JournalScience of the Total Environment
Volume661
DOIs
Publication statusPublished - 15 Apr 2019

Keywords

  • CaFe O
  • Co-precipitation
  • Photocatalysis
  • POME
  • Visible light

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