Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol

Andrew S. Weller; Christopher D. Andrews; Andrew D. Burrows; Michael Green; Jason M. Lynam; Mary F. Mahon; Cameron Jones

doi:10.1039/a905240b

Facile, metal promoted, oxidation of η⁴-1,3-diphosphacyclobutadiene by water or methanol

Andrew S. Weller
, Christopher D. Andrews
, Andrew D. Burrows
, Michael Green
, Jason M. Lynam
, Mary F. Mahon
, Cameron Jones

Research output: Contribution to journal › Article › Research › peer-review

10 Citations (Scopus)

Abstract

The new complexes [MoCl(CO)(η⁴-1,3-P₂C₂Bu(t)₂)(η⁵-L)] (L = C₅H₅ 1, C₅Me₅ 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){η³,λ³,λ⁵-PC₂Bu(t)₂-PH(OR)}(η⁵-C₅H₅)] (R = H, Me), which has also been structurally characterised for R = H.

Original language	English
Pages (from-to)	2147-2148
Number of pages	2
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/a905240b
Publication status	Published - 7 Nov 1999
Externally published	Yes

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@article{8826f0fa2937409986084baea436ecd4,

title = "Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol",

abstract = "The new complexes [MoCl(CO)(η4-1,3-P2C2Bu(t)2)(η5-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO)\{η3,λ3,λ5-PC2Bu(t)2-PH(OR)\}(η5-C5H5)] (R = H, Me), which has also been structurally characterised for R = H.",

author = "Weller, \{Andrew S.\} and Andrews, \{Christopher D.\} and Burrows, \{Andrew D.\} and Michael Green and Lynam, \{Jason M.\} and Mahon, \{Mary F.\} and Cameron Jones",

year = "1999",

month = nov,

day = "7",

doi = "10.1039/a905240b",

language = "English",

pages = "2147--2148",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "21",

}

TY - JOUR

T1 - Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol

AU - Weller, Andrew S.

AU - Andrews, Christopher D.

AU - Burrows, Andrew D.

AU - Green, Michael

AU - Lynam, Jason M.

AU - Mahon, Mary F.

AU - Jones, Cameron

PY - 1999/11/7

Y1 - 1999/11/7

N2 - The new complexes [MoCl(CO)(η4-1,3-P2C2Bu(t)2)(η5-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){η3,λ3,λ5-PC2Bu(t)2-PH(OR)}(η5-C5H5)] (R = H, Me), which has also been structurally characterised for R = H.

AB - The new complexes [MoCl(CO)(η4-1,3-P2C2Bu(t)2)(η5-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){η3,λ3,λ5-PC2Bu(t)2-PH(OR)}(η5-C5H5)] (R = H, Me), which has also been structurally characterised for R = H.

UR - https://www.scopus.com/pages/publications/0033533955

U2 - 10.1039/a905240b

DO - 10.1039/a905240b

M3 - Article

AN - SCOPUS:0033533955

SN - 1359-7345

SP - 2147

EP - 2148

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Facile, metal promoted, oxidation of η4-1,3-diphosphacyclobutadiene by water or methanol

Abstract

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Facile, metal promoted, oxidation of η⁴-1,3-diphosphacyclobutadiene by water or methanol