Extending the chemistry of carbones: P-N bond cleavage via an SN2′-like mechanism

Chitra Gurnani; Nemanja Orević; Senthilkumar Muthaiah; Dušan Dimić; Rakesh Ganguly; Milena Petković; Dragoslav Vidović

doi:10.1039/c5cc03194j

Extending the chemistry of carbones: P-N bond cleavage via an S_N2′-like mechanism

Chitra Gurnani, Nemanja Orević, Senthilkumar Muthaiah, Dušan Dimić, Rakesh Ganguly, Milena Petković, Dragoslav Vidović

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

The reactivity of nucleophilic carbodiphosphorane (C(PPh₃)₂, 1) and carbodicarbene (C(C(NMe)₂C₆H₄)₂, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl₂)₂ resulted in a unique P-N bond cleavage that, according to computational studies, occurred via an S_N2′-like mechanism. This journal is

Original language	English
Pages (from-to)	10762-10764
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	53
DOIs	https://doi.org/10.1039/c5cc03194j
Publication status	Published - 7 Jul 2015
Externally published	Yes

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10.1039/c5cc03194j

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abstract = "The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P-N bond cleavage that, according to computational studies, occurred via an SN2′-like mechanism. This journal is",

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year = "2015",

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doi = "10.1039/c5cc03194j",

language = "English",

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journal = "Chemical Communications",

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T1 - Extending the chemistry of carbones

T2 - P-N bond cleavage via an SN2′-like mechanism

AU - Gurnani, Chitra

AU - Orević, Nemanja

AU - Muthaiah, Senthilkumar

AU - Dimić, Dušan

AU - Ganguly, Rakesh

AU - Petković, Milena

AU - Vidović, Dragoslav

PY - 2015/7/7

Y1 - 2015/7/7

N2 - The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P-N bond cleavage that, according to computational studies, occurred via an SN2′-like mechanism. This journal is

AB - The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P-N bond cleavage that, according to computational studies, occurred via an SN2′-like mechanism. This journal is

UR - https://www.scopus.com/pages/publications/84934913857

U2 - 10.1039/c5cc03194j

DO - 10.1039/c5cc03194j

M3 - Article

AN - SCOPUS:84934913857

SN - 1359-7345

VL - 51

SP - 10762

EP - 10764

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

Extending the chemistry of carbones: P-N bond cleavage via an SN2′-like mechanism

Abstract

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Extending the chemistry of carbones: P-N bond cleavage via an S_N2′-like mechanism