Exploring the reactivity of N-alkynylated sulfoximines: [2 + 2]-cycloadditions

Ramona Pirwerdjan; Daniel Priebbenow; Peter Becker; Philip Lamers; Carsten Bolm

doi:10.1021/ol4026028

Exploring the reactivity of N-alkynylated sulfoximines: [2 + 2]-cycloadditions

Ramona Pirwerdjan, Daniel Priebbenow, Peter Becker, Philip Lamers, Carsten Bolm

Research output: Contribution to journal › Letter › Other

37 Citations (Scopus)

Abstract

To assess the potential of N-alkynylated sulfoximines as new (chiral) reagents for organic synthesis, their reactivity profile in numerous synthetic processes is under investigation. When reacted with ketenes, the alkynylated-sulfoximines undergo a [2 + 2]-cycloaddition process to afford sulfoximine-functionalized cyclobutenones in excellent yields.

Original language	English
Pages (from-to)	5397 - 5399
Number of pages	3
Journal	Organic Letters
Volume	15
Issue number	21
DOIs	https://doi.org/10.1021/ol4026028
Publication status	Published - 2013
Externally published	Yes

Access to Document

10.1021/ol4026028

Cite this

@article{dd3dcc94ccb84d9e913c7f6d01f665a5,

title = "Exploring the reactivity of N-alkynylated sulfoximines: [2 + 2]-cycloadditions",

abstract = "To assess the potential of N-alkynylated sulfoximines as new (chiral) reagents for organic synthesis, their reactivity profile in numerous synthetic processes is under investigation. When reacted with ketenes, the alkynylated-sulfoximines undergo a [2 + 2]-cycloaddition process to afford sulfoximine-functionalized cyclobutenones in excellent yields.",

author = "Ramona Pirwerdjan and Daniel Priebbenow and Peter Becker and Philip Lamers and Carsten Bolm",

year = "2013",

doi = "10.1021/ol4026028",

language = "English",

volume = "15",

pages = "5397 -- 5399",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Exploring the reactivity of N-alkynylated sulfoximines: [2 + 2]-cycloadditions

AU - Pirwerdjan, Ramona

AU - Priebbenow, Daniel

AU - Becker, Peter

AU - Lamers, Philip

AU - Bolm, Carsten

PY - 2013

Y1 - 2013

N2 - To assess the potential of N-alkynylated sulfoximines as new (chiral) reagents for organic synthesis, their reactivity profile in numerous synthetic processes is under investigation. When reacted with ketenes, the alkynylated-sulfoximines undergo a [2 + 2]-cycloaddition process to afford sulfoximine-functionalized cyclobutenones in excellent yields.

AB - To assess the potential of N-alkynylated sulfoximines as new (chiral) reagents for organic synthesis, their reactivity profile in numerous synthetic processes is under investigation. When reacted with ketenes, the alkynylated-sulfoximines undergo a [2 + 2]-cycloaddition process to afford sulfoximine-functionalized cyclobutenones in excellent yields.

UR - http://pubs.acs.org/doi/pdf/10.1021/ol4026028

UR - https://www.scopus.com/pages/publications/84887050209

U2 - 10.1021/ol4026028

DO - 10.1021/ol4026028

M3 - Letter

SN - 1523-7060

VL - 15

SP - 5397

EP - 5399

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

Exploring the reactivity of N-alkynylated sulfoximines: [2 + 2]-cycloadditions

Abstract

Access to Document

Other files and links

Cite this