Evaluation of some cyclic dipeptides as catalysts for the asymmetric hydrocyanation of aldehydes

W. Roy Jackson; Gamini S. Jayatilake; Barry R. Matthews; Colin Wilshire

doi:10.1071/CH9880203

Evaluation of some cyclic dipeptides as catalysts for the asymmetric hydrocyanation of aldehydes

W. Roy Jackson, Gamini S. Jayatilake, Barry R. Matthews, Colin Wilshire

School of Chemistry

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Abstract

A series of cyclic dipeptides has been prepared and evaluated as catalysts for the asymmetric hydrocyanation of benzaldehyde and 3-phenoxybenzaldehyde. Cyclo-(R, R)- or (S, S)-(phenylalanylhistidyl), previously reported by Inoue and his coworkers, has proven to be the most effective catalyst, giving high preparative and optical yields under appropriate conditions.

Original language	English
Pages (from-to)	203-213
Number of pages	11
Journal	Australian Journal of Chemistry
Volume	41
Issue number	2
DOIs	https://doi.org/10.1071/CH9880203
Publication status	Published - 1 Jan 1988

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abstract = "A series of cyclic dipeptides has been prepared and evaluated as catalysts for the asymmetric hydrocyanation of benzaldehyde and 3-phenoxybenzaldehyde. Cyclo-(R, R)- or (S, S)-(phenylalanylhistidyl), previously reported by Inoue and his coworkers, has proven to be the most effective catalyst, giving high preparative and optical yields under appropriate conditions.",

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N2 - A series of cyclic dipeptides has been prepared and evaluated as catalysts for the asymmetric hydrocyanation of benzaldehyde and 3-phenoxybenzaldehyde. Cyclo-(R, R)- or (S, S)-(phenylalanylhistidyl), previously reported by Inoue and his coworkers, has proven to be the most effective catalyst, giving high preparative and optical yields under appropriate conditions.

AB - A series of cyclic dipeptides has been prepared and evaluated as catalysts for the asymmetric hydrocyanation of benzaldehyde and 3-phenoxybenzaldehyde. Cyclo-(R, R)- or (S, S)-(phenylalanylhistidyl), previously reported by Inoue and his coworkers, has proven to be the most effective catalyst, giving high preparative and optical yields under appropriate conditions.

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JF - Australian Journal of Chemistry

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Evaluation of some cyclic dipeptides as catalysts for the asymmetric hydrocyanation of aldehydes

Abstract

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