Ethyl 1-[3-(1H-imidazol-1-yl)propyl]-2-(4-chlorophenyl)-1H-benzo[d] imidazole-5-carboxylate dihydrate

Yeong Keng Yoon; Mohamed Ashraf Ali; Ang Chee Wei; Ching Kheng Quah; Hoong Kun Fun

doi:10.1107/S1600536811033654

Ethyl 1-[3-(1H-imidazol-1-yl)propyl]-2-(4-chlorophenyl)-1H-benzo[d] imidazole-5-carboxylate dihydrate

Yeong Keng Yoon, Mohamed Ashraf Ali, Ang Chee Wei, Ching Kheng Quah, Hoong Kun Fun

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

In the title compound, C ₂₂H ₂₁ClN ₄O ₂·2H ₂O, the almostplanar benzimidazole ring system [maximum deviation 0.014 (1) Å] is inclined at angles of 36.32 (5) and 74.75 (7)° with respect to the phenyl and imidazole rings, respectively. In the crystal structure, the water molecules are linked to the organic molecules to form a threedimensional network via O - H⋯N and O - H⋯O hydrogen bonds. The packing is further consolidated by a pair of bifurcated C - H⋯O bonds, generating R ¹ 2(6) loops. C - H⋯π interactions are also observed.

Original language	English
Pages (from-to)	o2405
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	9
DOIs	https://doi.org/10.1107/S1600536811033654
Publication status	Published - Sept 2011
Externally published	Yes

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title = "Ethyl 1-[3-(1H-imidazol-1-yl)propyl]-2-(4-chlorophenyl)-1H-benzo[d] imidazole-5-carboxylate dihydrate",

abstract = "In the title compound, C 22H 21ClN 4O 2·2H 2O, the almostplanar benzimidazole ring system [maximum deviation 0.014 (1) {\AA}] is inclined at angles of 36.32 (5) and 74.75 (7)° with respect to the phenyl and imidazole rings, respectively. In the crystal structure, the water molecules are linked to the organic molecules to form a threedimensional network via O - H⋯N and O - H⋯O hydrogen bonds. The packing is further consolidated by a pair of bifurcated C - H⋯O bonds, generating R 1 2(6) loops. C - H⋯π interactions are also observed.",

author = "Yoon, {Yeong Keng} and Ali, {Mohamed Ashraf} and Wei, {Ang Chee} and Quah, {Ching Kheng} and Fun, {Hoong Kun}",

year = "2011",

month = sep,

doi = "10.1107/S1600536811033654",

language = "English",

volume = "67",

pages = "o2405",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "2056-9890",

publisher = "International Union of Crystallography (IUCr)",

number = "9",

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TY - JOUR

T1 - Ethyl 1-[3-(1H-imidazol-1-yl)propyl]-2-(4-chlorophenyl)-1H-benzo[d] imidazole-5-carboxylate dihydrate

AU - Yoon, Yeong Keng

AU - Ali, Mohamed Ashraf

AU - Wei, Ang Chee

AU - Quah, Ching Kheng

AU - Fun, Hoong Kun

PY - 2011/9

Y1 - 2011/9

N2 - In the title compound, C 22H 21ClN 4O 2·2H 2O, the almostplanar benzimidazole ring system [maximum deviation 0.014 (1) Å] is inclined at angles of 36.32 (5) and 74.75 (7)° with respect to the phenyl and imidazole rings, respectively. In the crystal structure, the water molecules are linked to the organic molecules to form a threedimensional network via O - H⋯N and O - H⋯O hydrogen bonds. The packing is further consolidated by a pair of bifurcated C - H⋯O bonds, generating R 1 2(6) loops. C - H⋯π interactions are also observed.

AB - In the title compound, C 22H 21ClN 4O 2·2H 2O, the almostplanar benzimidazole ring system [maximum deviation 0.014 (1) Å] is inclined at angles of 36.32 (5) and 74.75 (7)° with respect to the phenyl and imidazole rings, respectively. In the crystal structure, the water molecules are linked to the organic molecules to form a threedimensional network via O - H⋯N and O - H⋯O hydrogen bonds. The packing is further consolidated by a pair of bifurcated C - H⋯O bonds, generating R 1 2(6) loops. C - H⋯π interactions are also observed.

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M3 - Article

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SN - 2056-9890

VL - 67

SP - o2405

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

Ethyl 1-[3-(1H-imidazol-1-yl)propyl]-2-(4-chlorophenyl)-1H-benzo[d] imidazole-5-carboxylate dihydrate

Abstract

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