Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets: via bridging ligand modification

Stuart K. Langley; Daniel P. Wielechowski; Boujemaa Moubaraki; Keith S. Murray

doi:10.1039/c6cc06152d

Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII₂LnIII₂} single-molecule magnets: via bridging ligand modification

Stuart K. Langley, Daniel P. Wielechowski, Boujemaa Moubaraki, Keith S. Murray

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

41 Citations (Scopus)

Abstract

Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.

Original language	English
Pages (from-to)	10976-10979
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	73
DOIs	https://doi.org/10.1039/c6cc06152d
Publication status	Published - 21 Sep 2016

Access to Document

10.1039/c6cc06152d

Cite this

@article{ba1fd6e9f5f34287af240afd09d42397,

title = "Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets: via bridging ligand modification",

abstract = "Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.",

author = "Langley, {Stuart K.} and Wielechowski, {Daniel P.} and Boujemaa Moubaraki and Murray, {Keith S.}",

year = "2016",

month = sep,

day = "21",

doi = "10.1039/c6cc06152d",

language = "English",

volume = "52",

pages = "10976--10979",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "73",

}

Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII₂LnIII₂} single-molecule magnets : via bridging ligand modification. / Langley, Stuart K.; Wielechowski, Daniel P.; Moubaraki, Boujemaa; Murray, Keith S.

In: Chemical Communications, Vol. 52, No. 73, 21.09.2016, p. 10976-10979.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets

T2 - via bridging ligand modification

AU - Langley, Stuart K.

AU - Wielechowski, Daniel P.

AU - Moubaraki, Boujemaa

AU - Murray, Keith S.

PY - 2016/9/21

Y1 - 2016/9/21

N2 - Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.

AB - Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.

UR - http://www.scopus.com/inward/record.url?scp=84984920275&partnerID=8YFLogxK

U2 - 10.1039/c6cc06152d

DO - 10.1039/c6cc06152d

M3 - Article

AN - SCOPUS:84984920275

VL - 52

SP - 10976

EP - 10979

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 73

ER -

Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets: via bridging ligand modification

Abstract

Access to Document

Other files and links

Cite this

Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII₂LnIII₂} single-molecule magnets: via bridging ligand modification