Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets: via bridging ligand modification

Stuart K. Langley; Daniel P. Wielechowski; Boujemaa Moubaraki; Keith S. Murray

doi:10.1039/c6cc06152d

Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII₂LnIII₂} single-molecule magnets: via bridging ligand modification

Stuart K. Langley, Daniel P. Wielechowski, Boujemaa Moubaraki, Keith S. Murray

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

59 Citations (Scopus)

Abstract

Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.

Original language	English
Pages (from-to)	10976-10979
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	73
DOIs	https://doi.org/10.1039/c6cc06152d
Publication status	Published - 21 Sept 2016

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10.1039/c6cc06152d

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abstract = "Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.",

author = "Langley, {Stuart K.} and Wielechowski, {Daniel P.} and Boujemaa Moubaraki and Murray, {Keith S.}",

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Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII₂LnIII₂} single-molecule magnets: via bridging ligand modification. / Langley, Stuart K.; Wielechowski, Daniel P.; Moubaraki, Boujemaa et al.
In: Chemical Communications, Vol. 52, No. 73, 21.09.2016, p. 10976-10979.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets

T2 - via bridging ligand modification

AU - Langley, Stuart K.

AU - Wielechowski, Daniel P.

AU - Moubaraki, Boujemaa

AU - Murray, Keith S.

PY - 2016/9/21

Y1 - 2016/9/21

N2 - Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.

AB - Replacing bridging benzoate ligands with 2-chloro-4,5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.

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U2 - 10.1039/c6cc06152d

DO - 10.1039/c6cc06152d

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VL - 52

SP - 10976

EP - 10979

JO - Chemical Communications

JF - Chemical Communications

IS - 73

ER -

Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets: via bridging ligand modification

Abstract

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Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII₂LnIII₂} single-molecule magnets: via bridging ligand modification