Enhancing electrocatalytic activity of perovskite oxides by tuning cation deficiency for oxygen reduction and evolution reactions

Yinlong Zhu, Wei Zhou, Jie Yu, Yubo Chen, Meilin Liu, Zongping Shao

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525 Citations (Scopus)


Development of cost-effective and efficient electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is of prime importance to emerging renewable energy technologies. Here, we report a simple and effective strategy for enhancing ORR and OER electrocatalytic activity in alkaline solution by introducing A-site cation deficiency in LaFeO3 perovskite; the enhancement effect is more pronounced for the OER than the ORR. Among the A-site cation deficient perovskites studied, La0.95FeO3-δ (L0.95F) demonstrates the highest ORR and OER activity and, hence, the best bifunctionality. The dramatic enhancement is attributed to the creation of surface oxygen vacancies and a small amount of Fe4+ species. This work highlights the importance of tuning cation deficiency in perovskites as an effective strategy for enhancing ORR and OER activity for applications in various oxygen-based energy storage and conversion processes.

Original languageEnglish
Pages (from-to)1691-1697
Number of pages7
JournalChemistry of Materials
Issue number6
Publication statusPublished - 22 Mar 2016
Externally publishedYes

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